Quantification of surface composition and segregation on AuAg bimetallic nanoparticles by MALDI MS

In this work we show that it is possible to use MALDI-TOF as a tool to quantify the atomic composition and to describe the phase segragation of the surface of ligand-coated, bimetallic AuAg nanoparticles. Our investigation shows that AuAg nanoparticles of various compositions exhibit core-shell heterogeneity with surface enrichment of Ag. A Monte-Carlo type simulation demonstrates that the surface Au and Ag atoms arrange in a random fashion.

Medienart:

E-Artikel

Erscheinungsjahr:

2020

Erschienen:

2020

Enthalten in:

Zur Gesamtaufnahme - volume:12

Enthalten in:

Nanoscale - 12(2020), 44 vom: 19. Nov., Seite 22639-22644

Sprache:

Englisch

Beteiligte Personen:

Liao, Suiyang [VerfasserIn]
Luo, Zhi [VerfasserIn]
Metternich, Jonas Bastian [VerfasserIn]
Zenobi, Renato [VerfasserIn]
Stellacci, Francesco [VerfasserIn]

Links:

Volltext

Themen:

Journal Article

Anmerkungen:

Date Revised 20.11.2020

published: Print

Citation Status PubMed-not-MEDLINE

doi:

10.1039/d0nr05061j

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM317193759