High-performance magnesium/sodium hybrid ion battery based on sodium vanadate oxide for reversible storage of Na+ and Mg2+
Magnesium ion batteries (MIBs) are a potential field for the energy storage of the future but are restricted by insufficient rate capability and rapid capacity degradation. Magnesium-sodium hybrid ion batteries (MSHBs) are an effective way to address these problems. Here, we report a new type of MSHBs that use layered sodium vanadate ((Na, Mn)V8O20 5H2O, Mn-NVO) cathodes coupled with an organic 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) anode in Mg2+/Na+ hybrid electrolytes. During electrochemical cycling, Mg2+ and Na+ co-participate in the cathode reactions, and the introduction of Na+ promotes the structural stability of the Mn-NVO cathode, as cleared by several ex-situ characterizations. Consequently, the Mn-NVO cathode presents great specific capacity (249.9 mAh g-1 at 300 mA g-1) and cycling (1500 cycles at 1500 mA g-1) in the Mg2+/Na+ hybrid electrolytes. Besides, full battery displays long lifespan with 10,000 cycles at 1000 mA g-1. The rate performance and cycling stability of MSHBs have been improved by an economical and scalable method, and the mechanism for these improvements was discussed..
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Preprint| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
arXiv.org - (2024) vom: 15. Apr. Zur Gesamtaufnahme - year:2024 |
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| Sprache: |
Englisch |
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| Beteiligte Personen: |
Wang, Xiaoke [VerfasserIn] |
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| Links: |
Volltext [kostenfrei] |
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| PPN (Katalog-ID): |
XAR04326932X |
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| 100 | 1 | |a Wang, Xiaoke |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a High-performance magnesium/sodium hybrid ion battery based on sodium vanadate oxide for reversible storage of Na+ and Mg2+ |
| 264 | 1 | |c 2024 | |
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| 520 | |a Magnesium ion batteries (MIBs) are a potential field for the energy storage of the future but are restricted by insufficient rate capability and rapid capacity degradation. Magnesium-sodium hybrid ion batteries (MSHBs) are an effective way to address these problems. Here, we report a new type of MSHBs that use layered sodium vanadate ((Na, Mn)V8O20 5H2O, Mn-NVO) cathodes coupled with an organic 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) anode in Mg2+/Na+ hybrid electrolytes. During electrochemical cycling, Mg2+ and Na+ co-participate in the cathode reactions, and the introduction of Na+ promotes the structural stability of the Mn-NVO cathode, as cleared by several ex-situ characterizations. Consequently, the Mn-NVO cathode presents great specific capacity (249.9 mAh g-1 at 300 mA g-1) and cycling (1500 cycles at 1500 mA g-1) in the Mg2+/Na+ hybrid electrolytes. Besides, full battery displays long lifespan with 10,000 cycles at 1000 mA g-1. The rate performance and cycling stability of MSHBs have been improved by an economical and scalable method, and the mechanism for these improvements was discussed. | ||
| 650 | 4 | |a Physics - Materials Science |7 (dpeaa)DE-84 | |
| 650 | 4 | |a Physics - Chemical Physics |7 (dpeaa)DE-84 | |
| 650 | 4 | |a 530 |7 (dpeaa)DE-84 | |
| 700 | 1 | |a Li, Titi |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Xixi |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Yaxin |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Hongfei |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Hai-Feng |e verfasserin |4 aut | |
| 700 | 1 | |a Zhao, Gang |e verfasserin |4 aut | |
| 700 | 1 | |a Han, Cuiping |e verfasserin |4 aut | |
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