Ortho‐ C− H Methylation and Ipso‐C−O Alkenylation of Aryl Triflates via Catellani Strategy
Abstract The ortho C−H methylation and ipso C−O alkenylation of aryl triflates was regio‐selectively achieved in one pot by palladium/norbornene (NBE) synergistic catalysis. This work provides an efficient method for preparing poly‐substituted aromatics with (deuterated) methyl and alkenyl groups from the readily available phenoxides..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:27 |
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| Enthalten in: |
European Journal of Organic Chemistry - 27(2024), 8 |
| Beteiligte Personen: |
Yang, Lei [VerfasserIn] |
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| Anmerkungen: |
© 2024 Wiley‐VCH GmbH |
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| Umfang: |
5 |
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| doi: |
10.1002/ejoc.202301245 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
WLY01752931X |
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| 520 | |a Abstract The ortho C−H methylation and ipso C−O alkenylation of aryl triflates was regio‐selectively achieved in one pot by palladium/norbornene (NBE) synergistic catalysis. This work provides an efficient method for preparing poly‐substituted aromatics with (deuterated) methyl and alkenyl groups from the readily available phenoxides. | ||
| 700 | 1 | |a Fu, Jianbin |4 aut | |
| 700 | 1 | |a Tan, Qihang |4 aut | |
| 700 | 1 | |a Li, Chenglong |4 aut | |
| 700 | 1 | |a Zhang, Shuo |4 aut | |
| 700 | 1 | |a Li, Chunya |4 aut | |
| 700 | 1 | |a Liu, Long |4 aut | |
| 700 | 1 | |a Huang, Tianzeng |4 aut | |
| 700 | 1 | |a Chen, Tieqiao |4 aut | |
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