Frustration in Super‐Ionic Conductors Unraveled by the Density of Atomistic States
Abstract The frustration in super‐ionic conductors enables their exceptionally high ionic conductivities, which are desired for many technological applications including batteries and fuel cells. A key challenge in the study of frustration is the difficulties in analyzing a large number of disordered atomistic configurations. Using lithium super‐ionic conductors as model systems, we propose and demonstrate the density of atomistic states (DOAS) analytics to quantitatively characterize the onset and degree of disordering, reveal the energetics of local disorder, and elucidate how the frustration enhances diffusion through the broadening and overlapping of the energy levels of atomistic states. Furthermore, material design strategies aided by the DOAS are devised and demonstrated for new super‐ionic conductors. The DOAS is generally applicable analytics for unraveling fundamental mechanisms in complex atomistic systems and guiding material design..
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2023 |
|---|---|
| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:62 |
|---|---|
| Enthalten in: |
Angewandte Chemie International Edition - 62(2023), 15 |
| Beteiligte Personen: |
Wang, Shuo [VerfasserIn] |
|---|
| Anmerkungen: |
© 2023 Wiley‐VCH GmbH |
|---|
| Umfang: |
8 |
|---|
| doi: |
10.1002/anie.202215544 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
WLY015018865 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | WLY015018865 | ||
| 003 | DE-627 | ||
| 005 | 20231111124824.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231111s2023 xx |||||o 00| ||und c | ||
| 024 | 7 | |a 10.1002/anie.202215544 |2 doi | |
| 028 | 5 | 2 | |a 2023-11-11_ANIE_2023_62_15.zip.xml |
| 035 | |a (DE-627)WLY015018865 | ||
| 035 | |a (WILEY)ANIE202215544 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 100 | 1 | |a Wang, Shuo |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Frustration in Super‐Ionic Conductors Unraveled by the Density of Atomistic States |
| 264 | 1 | |c 2023 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a © 2023 Wiley‐VCH GmbH | ||
| 520 | |a Abstract The frustration in super‐ionic conductors enables their exceptionally high ionic conductivities, which are desired for many technological applications including batteries and fuel cells. A key challenge in the study of frustration is the difficulties in analyzing a large number of disordered atomistic configurations. Using lithium super‐ionic conductors as model systems, we propose and demonstrate the density of atomistic states (DOAS) analytics to quantitatively characterize the onset and degree of disordering, reveal the energetics of local disorder, and elucidate how the frustration enhances diffusion through the broadening and overlapping of the energy levels of atomistic states. Furthermore, material design strategies aided by the DOAS are devised and demonstrated for new super‐ionic conductors. The DOAS is generally applicable analytics for unraveling fundamental mechanisms in complex atomistic systems and guiding material design. | ||
| 700 | 1 | |a Liu, Yunsheng |4 aut | |
| 700 | 1 | |a Mo, Yifei |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Angewandte Chemie International Edition |g 62(2023), 15 |w (DE-627)WLY001913387 |x 15213773 |7 nnns |
| 773 | 1 | 8 | |g volume:62 |g year:2023 |g number:15 |g extent:8 |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_WLY | ||
| 951 | |a AR | ||
| 952 | |d 62 |j 2023 |e 15 |g 8 | ||