Alkoxymigration onto α‐Imino Gold Carbenes for Constructing Propellane‐Type Indolines
Abstract We developed a new reaction entity of α‐imino gold carbenes involving alkoxy migration. The reaction would proceed through oxonium ylide formation by intramolecular addition of an alkoxy group, carbon‐oxygen bond cleavage, and carbon−carbon bond formation. We achieved an efficient gold‐catalyzed synthesis of indoline‐propellanes via a one‐pot sequence by using ethylene glycol as a trapping reagent..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:12 |
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| Enthalten in: |
Asian Journal of Organic Chemistry - 12(2023), 7 |
| Beteiligte Personen: |
Greiner, Luca C. [VerfasserIn] |
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| Anmerkungen: |
© 2023 Wiley‐VCH GmbH |
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| Umfang: |
4 |
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| doi: |
10.1002/ajoc.202300232 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
WLY014939630 |
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| 520 | |a Abstract We developed a new reaction entity of α‐imino gold carbenes involving alkoxy migration. The reaction would proceed through oxonium ylide formation by intramolecular addition of an alkoxy group, carbon‐oxygen bond cleavage, and carbon−carbon bond formation. We achieved an efficient gold‐catalyzed synthesis of indoline‐propellanes via a one‐pot sequence by using ethylene glycol as a trapping reagent. | ||
| 700 | 1 | |a Arichi, Norihito |4 aut | |
| 700 | 1 | |a Inuki, Shinsuke |4 aut | |
| 700 | 1 | |a Ohno, Hiroaki |4 aut | |
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