TAD Click Chemistry on Aliphatic Polycarbonates : A First Step Toward Tailor‐Made Materials
For the first time, the effectiveness of triazolinedione (TAD) click chemistry onto aliphatic polycarbonates (APC) is demonstrated. Statistic copolymers carrying click‐reactive conjugated diene (in a ratio of 10%) are synthesized via organocatalyzed ring‐opening polymerization. The highly efficient click reaction of TADs carrying simple butyl and phenyl functions are confirmed by1 H‐NMR and DSC. Network formation using a bivalent TAD is also performed and simply characterized by DSC. This post‐polymerization functionalization of biocompatible and biodegradable APC pave the way to easy and versatile “on‐demand” materials design..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:40 |
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| Enthalten in: |
Macromolecular Rapid Communications - 40(2019), 7 |
| Beteiligte Personen: |
Baroni, Alexandra [VerfasserIn] |
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| BKL: |
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| Anmerkungen: |
© 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Umfang: |
5 |
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| doi: |
10.1002/marc.201800743 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
WLY009848770 |
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| 520 | |a For the first time, the effectiveness of triazolinedione (TAD) click chemistry onto aliphatic polycarbonates (APC) is demonstrated. Statistic copolymers carrying click‐reactive conjugated diene (in a ratio of 10%) are synthesized via organocatalyzed ring‐opening polymerization. The highly efficient click reaction of TADs carrying simple butyl and phenyl functions are confirmed by1 H‐NMR and DSC. Network formation using a bivalent TAD is also performed and simply characterized by DSC. This post‐polymerization functionalization of biocompatible and biodegradable APC pave the way to easy and versatile “on‐demand” materials design. | ||
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