Transparent glass‐ceramics in the TeO2–InF3 system
Abstract A crystallization study of the TeO2–InF3 glass system shows that the specific glass composition 75TeO2–25InF3 stabilizes a novel cubic anti‐glass phase within the glass matrix upon heat treatment. This peculiar crystalline phase also called “glass of anions” exhibits an interesting order/disorder coexistence, that is, a long‐range cation order but with a highly disordered anion sublattice. The thermal properties, structure and microstructure of the parent glass and corresponding glass‐ceramics have been studied. Finally, the luminescence of Yb3+‐doped glass‐ceramics has been characterized, which confirmed the presence of the disordered anti‐glass phase..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2022 |
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| Erschienen: |
2022 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:13 |
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| Enthalten in: |
International Journal of Applied Glass Science - 13(2022), 4, Seite 568-575 |
| Beteiligte Personen: |
Piotrowski, Rémi [VerfasserIn] |
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| BKL: |
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| Anmerkungen: |
© 2022 The American Ceramic Society and Wiley Periodicals LLC. |
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| Umfang: |
8 |
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| doi: |
10.1111/ijag.16581 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| 520 | |a Abstract A crystallization study of the TeO2–InF3 glass system shows that the specific glass composition 75TeO2–25InF3 stabilizes a novel cubic anti‐glass phase within the glass matrix upon heat treatment. This peculiar crystalline phase also called “glass of anions” exhibits an interesting order/disorder coexistence, that is, a long‐range cation order but with a highly disordered anion sublattice. The thermal properties, structure and microstructure of the parent glass and corresponding glass‐ceramics have been studied. Finally, the luminescence of Yb3+‐doped glass‐ceramics has been characterized, which confirmed the presence of the disordered anti‐glass phase. | ||
| 700 | 1 | |a Benchorfi, Hasnaa |4 aut | |
| 700 | 1 | |a Laval, Jean‐Paul |4 aut | |
| 700 | 1 | |a Duclère, Jean‐René |4 aut | |
| 700 | 1 | |a Genevois, Cécile |4 aut | |
| 700 | 1 | |a Carles, Pierre |4 aut | |
| 700 | 1 | |a Chenu, Sébastien |4 aut | |
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| 700 | 1 | |a Cornette, Julie |4 aut | |
| 700 | 1 | |a Thomas, Philippe |4 aut | |
| 700 | 1 | |a Delaizir, Gaëlle |4 aut | |
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