The low‐temperature barium fluoridozirconate variety α‐BaZr2 F10

The low‐temperature triclinic variety α‐BaZr2 F10 constitutes a new structure type, less symmetrical than the higher‐temperature β‐variety. It is based on the stacking of double sheets of Zr polyhedra, connecting three different kinds of ZrF7 polyhedra and one ZrF8 polyhedron via vertices and edges, separated by corrugated Ba2+ layers. It is compared to the high‐temperature β‐variety, directly recrystallizing from barium fluoridozirconate glass, and also to BaTe2 F10 and KTe2 F9..

Medienart:

E-Artikel

Erscheinungsjahr:

2019

Erschienen:

2019

Enthalten in:

Zur Gesamtaufnahme - volume:75

Enthalten in:

Acta Crystallographica Section C - 75(2019), 11, Seite 1482-1487

Beteiligte Personen:

Laval, Jean-Paul [VerfasserIn]

BKL:

38.31

33.61

35.90

Umfang:

5

doi:

10.1107/S205322961901297X

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

WLY002555565