Experimental Investigation and Thermodynamic Assessment of Phase Equilibria at the Ti-Mn side in the Ti-Mn-Mo Ternary System
Abstract The phase relationships of the Ti-Mn-Mo ternary system on the Ti-Mn side at 900 and 1000 °C were experimentally studied based on microstructure and phase constituents from the equilibrated alloys using electron probe microanalysis, scanning electron microscopy, and X-ray diffraction. The solubilities of Mo in the βTiMn, $ TiMn_{2} $, $ TiMn_{3} $ and $ TiMn_{4} $ phases of the Ti-Mn system were measured. A three-phase region and seven two-phase regions were experimentally determined. No ternary compounds were found. Based on the experimental data and the thermodynamic descriptions of the three binary sub-systems available in the literature, a set of thermodynamic parameters of the Ti-Mn-Mo ternary system was obtained. The calculated isothermal sections and vertical sections agree well with the experimental results. The calculated liquidus projection and invariant reaction scheme of the Ti-Mn-Mo ternary system are also presented. The present work can provide essential experimental and thermodynamic data for the design of biocompatible medical titanium alloys..
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2024 |
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Erschienen: |
2024 |
Enthalten in: |
Zur Gesamtaufnahme - volume:45 |
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Enthalten in: |
Journal of phase equilibria and diffusion - 45(2024), 1 vom: 29. Jan., Seite 56-74 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Wang, Cuiping [VerfasserIn] |
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Links: |
Volltext [lizenzpflichtig] |
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Themen: |
Isothermal section |
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Anmerkungen: |
© ASM International 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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doi: |
10.1007/s11669-024-01083-1 |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
SPR05526705X |
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520 | |a Abstract The phase relationships of the Ti-Mn-Mo ternary system on the Ti-Mn side at 900 and 1000 °C were experimentally studied based on microstructure and phase constituents from the equilibrated alloys using electron probe microanalysis, scanning electron microscopy, and X-ray diffraction. The solubilities of Mo in the βTiMn, $ TiMn_{2} $, $ TiMn_{3} $ and $ TiMn_{4} $ phases of the Ti-Mn system were measured. A three-phase region and seven two-phase regions were experimentally determined. No ternary compounds were found. Based on the experimental data and the thermodynamic descriptions of the three binary sub-systems available in the literature, a set of thermodynamic parameters of the Ti-Mn-Mo ternary system was obtained. The calculated isothermal sections and vertical sections agree well with the experimental results. The calculated liquidus projection and invariant reaction scheme of the Ti-Mn-Mo ternary system are also presented. The present work can provide essential experimental and thermodynamic data for the design of biocompatible medical titanium alloys. | ||
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