Syntheses, Structures, and Photoluminescence Properties of Two New Zinc(II) Coordination Polymers Constructed by Rigid Carboxylic Acid Ligand
Abstract Two new coordination polymers [Zn(L)(Bpa)·$ H_{2} $O]n (I) and [Zn(L)(Bip)]n (II) ($ H_{2} $L is 4‑hydroxyisophthalic acid, Bpa is 1,2-bis(4-pyridyl)ethane, Bip is 3,5-bis(imidazole-1-yl)pyridine) have been prepared and characterized by element analysis, powder X-ray diffraction, and single-crystal X-ray diffraction (CCDC nos. 2073592 (I), 2073594 (II)). The single crystal X-ray diffraction studies reveal that compound I is a 1D chain structure, in which zinc(II) is four-coordinated with a tetrahedral geometry. Complex II is a 2D layer structure, in which zinc(II) is four-coordinated. Complexes I and II are further extended into three-dimensional supramolecular network via hydrogen bonds and π···π interactions. The solid-state luminescent properties of compounds I and II have been investigated..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:68 |
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| Enthalten in: |
Russian journal of inorganic chemistry - 68(2023), 7 vom: 19. Juni, Seite 875-882 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Li, Y. P. [VerfasserIn] |
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| Links: |
Volltext [lizenzpflichtig] |
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| Anmerkungen: |
© Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 7, pp. 875–882. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. |
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| doi: |
10.1134/S0036023622602872 |
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| Förderinstitution / Projekttitel: |
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SPR054085896 |
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| 100 | 1 | |a Li, Y. P. |e verfasserin |4 aut | |
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| 500 | |a © Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 7, pp. 875–882. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. | ||
| 520 | |a Abstract Two new coordination polymers [Zn(L)(Bpa)·$ H_{2} $O]n (I) and [Zn(L)(Bip)]n (II) ($ H_{2} $L is 4‑hydroxyisophthalic acid, Bpa is 1,2-bis(4-pyridyl)ethane, Bip is 3,5-bis(imidazole-1-yl)pyridine) have been prepared and characterized by element analysis, powder X-ray diffraction, and single-crystal X-ray diffraction (CCDC nos. 2073592 (I), 2073594 (II)). The single crystal X-ray diffraction studies reveal that compound I is a 1D chain structure, in which zinc(II) is four-coordinated with a tetrahedral geometry. Complex II is a 2D layer structure, in which zinc(II) is four-coordinated. Complexes I and II are further extended into three-dimensional supramolecular network via hydrogen bonds and π···π interactions. The solid-state luminescent properties of compounds I and II have been investigated. | ||
| 700 | 1 | |a Li, G. L. |4 aut | |
| 700 | 1 | |a Xin, L. Y. |4 aut | |
| 700 | 1 | |a Li, X. L. |4 aut | |
| 700 | 1 | |a Liu, G. Z. |4 aut | |
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