Diiron butane-2,3-dithiolate complexes with monophosphine coligands: synthesis, characterization, and electrochemistry
Abstract In this paper, three diiron butane-2,3-dithiolate complexes [$ Fe_{2} $(CO)5L{µ-SCH($ CH_{3} $)CH($ CH_{3} $)S}] [L = P(4-$ C_{6} %$ H_{4} $F)3, 2; P(4-$ C_{6} %$ H_{4} %$ OCH_{3} $)3, 3; P(3-$ C_{6} %$ H_{4} $Cl)3, 4] have been synthesized by CO substitution of the starting complex [$ Fe_{2} $(CO)6{µ-SCH($ CH_{3} $)CH($ CH_{3} $)S}] (1) with the corresponding monophosphine coligands in the presence of $ Me_{3} $NO·$ 2H_{2} $O as the decarbonylating agent in 61‒74% yields. These complexes have been characterized by elemental analysis, IR, NMR spectroscopy, and single-crystal X-ray diffraction analysis. In addition, electrochemical studies revealed that these complexes can catalyze the reduction of proton to $ H_{2} $ in the presence of acetic acid under the electrochemical conditions..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:45 |
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| Enthalten in: |
Transition metal chemistry - 45(2019), 1 vom: 17. Sept., Seite 47-53 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Lin, Hui-Min [VerfasserIn] |
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| Links: |
Volltext [lizenzpflichtig] |
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| BKL: |
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| doi: |
10.1007/s11243-019-00355-x |
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| PPN (Katalog-ID): |
SPR018102891 |
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| 520 | |a Abstract In this paper, three diiron butane-2,3-dithiolate complexes [$ Fe_{2} $(CO)5L{µ-SCH($ CH_{3} $)CH($ CH_{3} $)S}] [L = P(4-$ C_{6} %$ H_{4} $F)3, 2; P(4-$ C_{6} %$ H_{4} %$ OCH_{3} $)3, 3; P(3-$ C_{6} %$ H_{4} $Cl)3, 4] have been synthesized by CO substitution of the starting complex [$ Fe_{2} $(CO)6{µ-SCH($ CH_{3} $)CH($ CH_{3} $)S}] (1) with the corresponding monophosphine coligands in the presence of $ Me_{3} $NO·$ 2H_{2} $O as the decarbonylating agent in 61‒74% yields. These complexes have been characterized by elemental analysis, IR, NMR spectroscopy, and single-crystal X-ray diffraction analysis. In addition, electrochemical studies revealed that these complexes can catalyze the reduction of proton to $ H_{2} $ in the presence of acetic acid under the electrochemical conditions. | ||
| 700 | 1 | |a Wang, Ling-Hui |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Xu-Feng |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Xing-Hai |e verfasserin |4 aut | |
| 700 | 1 | |a Jiang, Zhong-Qing |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Transition metal chemistry |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 |g 45(2019), 1 vom: 17. Sept., Seite 47-53 |w (DE-627)SPR018086276 |w (DE-600)1501083-1 |x 1572-901X |7 nnns |
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