Synthesis of trinuclear $ Cu^{II} $-complex with tris(4-triphenylmethylphenoxy)-substituted hemihexaphyrazine and radioprotective properties of its water-soluble form
Abstract A condensation of 2,5-diamino-1,3,4-thiadiazole with the products of the in situ reaction of 1,2-dicyano-4-(4-triphenylmethylphenoxy)benzene with sodium alkoxides in a mixture of butanol—methanol furnished a trisubstituted ABABAB-type macroheterocycle (hemihexaphyrazine). A 3 : 1 trinuclear complex was synthesized by the reaction of the macrocycle with copper(II) acetate. The compounds obtained were characterized by IR spectroscopy, UV-vis spectroscopy, mass spectrometry, as well as by elemental analysis. Radioprotective properties of the water-soluble form of the complex were studied.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2015 |
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| Erschienen: |
2015 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:64 |
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| Enthalten in: |
Russian chemical bulletin - 64(2015), 7 vom: Juli, Seite 1610-1615 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Danilova, E. A. [VerfasserIn] |
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| Links: |
Volltext [lizenzpflichtig] |
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| BKL: |
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| doi: |
10.1007/s11172-015-1049-5 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
SPR017331668 |
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| 245 | 1 | 0 | |a Synthesis of trinuclear $ Cu^{II} $-complex with tris(4-triphenylmethylphenoxy)-substituted hemihexaphyrazine and radioprotective properties of its water-soluble form |
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| 520 | |a Abstract A condensation of 2,5-diamino-1,3,4-thiadiazole with the products of the in situ reaction of 1,2-dicyano-4-(4-triphenylmethylphenoxy)benzene with sodium alkoxides in a mixture of butanol—methanol furnished a trisubstituted ABABAB-type macroheterocycle (hemihexaphyrazine). A 3 : 1 trinuclear complex was synthesized by the reaction of the macrocycle with copper(II) acetate. The compounds obtained were characterized by IR spectroscopy, UV-vis spectroscopy, mass spectrometry, as well as by elemental analysis. Radioprotective properties of the water-soluble form of the complex were studied | ||
| 700 | 1 | |a Islyaikin, M. K. |e verfasserin |4 aut | |
| 700 | 1 | |a Shtrygol´, S. Yu. |e verfasserin |4 aut | |
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