Nucleophilic addition of amide anions to 1-methyl-5(6,7,8)-nitroquinolinium salts
The stable adducts, N-(1-methyl-5(6,7,8)-nitro-1,2-dihydroquinolin-2-yl)benzamides were synthesized for the first time by the action of amide anions of aromatic acids on the N-methyl salts of 5-, 6-, 7-, and 8-nitroquinolines in anhydrous MeCN. Oxidative dehydrogenation of these amides afforded aroylimino derivatives of the corresponding 1-methyl-5(6,7,8)-nitro-2-quinolones..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:55 |
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| Enthalten in: |
Chemistry of heterocyclic compounds - 55(2019), 8 vom: Aug., Seite 739-747 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Avakyan, Elena K. [VerfasserIn] |
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| Links: |
Volltext [lizenzpflichtig] |
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| BKL: | |
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| Themen: |
-methyl cations |
| doi: |
10.1007/s10593-019-02529-y |
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| funding: |
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SPR011632100 |
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| 520 | |a The stable adducts, N-(1-methyl-5(6,7,8)-nitro-1,2-dihydroquinolin-2-yl)benzamides were synthesized for the first time by the action of amide anions of aromatic acids on the N-methyl salts of 5-, 6-, 7-, and 8-nitroquinolines in anhydrous MeCN. Oxidative dehydrogenation of these amides afforded aroylimino derivatives of the corresponding 1-methyl-5(6,7,8)-nitro-2-quinolones. | ||
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| 650 | 4 | |a nucleophilic addition |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Amangasieva, Gulminat А. |e verfasserin |4 aut | |
| 700 | 1 | |a Demidov, Oleg P. |e verfasserin |4 aut | |
| 700 | 1 | |a Borovleva, Anastasia А. |e verfasserin |4 aut | |
| 700 | 1 | |a Beketova, Elena S. |e verfasserin |4 aut | |
| 700 | 1 | |a Nechaeva, Oksana А. |e verfasserin |4 aut | |
| 700 | 1 | |a Borovlev, Ivan V. |e verfasserin |4 aut | |
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