Enhanced hydrogen production via methanolysis and energy storage on novel poplar sawdust-based biomass-derived activated carbon catalyst
The originality of our current work is based on the use of $ H_{3} $$ PO_{4} $ functionalized waste poplar sawdust as a supercapacitor electrode material and catalyst for $ NaBH_{4} $ methanolysis reaction. $ N_{2} $ adsorption–desorption, scanning electron microscopy with energy-dispersive X-ray spectrometry (SEM–EDX), Fourier-transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) are utilized for characterization of the activated carbon (AC). In the first stage of our study, the effect of $ H_{3} $$ PO_{4} $ ratios and carbonization temperature on the hydrogen generation rate (HGR) is investigated and optimized. The optimum $ H_{3} $$ PO_{4} $ and carbonization temperature for $ NaBH_{4} $ methanolysis on AC are determined as 4:1 and 600 °C, respectively. The optimum points for the methanol concentration, $ NaBH_{4} $ concentration, reaction temperature, and catalyst amount affecting the HGR values for the methanolysis reaction on the KV4-600 catalyst under these conditions are determined as 4 ml, 1.25 wt% $ NaBH_{4} $, 60 °C, and 50 mg, respectively. Moreover, the HGR, activation energy, and the reaction completion duration under optimized reaction conditions are obtained as 19,050.00 mL $ min^{−1} $ $ g_{cat} $−1, 11.76 kJ $ mol^{−1} $, and 60 s, respectively. The performance of the KV4-600 as a supercapacitor electrode material is evaluated by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS). The specific capacitance of the KV4-600 at a specific current of 0.25 A $ g^{−1} $ is found to be 161.15 F $ g^{−1} $. KV4-600 shows satisfactory results both as supercapacitor electrode material and as catalyst for $ NaBH_{4} $ methanolysis. Graphical Abstract.
Medienart: |
E-Artikel |
---|
Erscheinungsjahr: |
2023 |
---|---|
Erschienen: |
2023 |
Enthalten in: |
Zur Gesamtaufnahme - volume:53 |
---|---|
Enthalten in: |
Journal of applied electrochemistry - 53(2023), 8 vom: 14. März, Seite 1643-1655 |
Sprache: |
Englisch |
---|
Beteiligte Personen: |
Kaya, Sefika [VerfasserIn] |
---|
Links: |
Volltext [lizenzpflichtig] |
---|
BKL: | |
---|---|
Themen: |
Anmerkungen: |
© The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
---|
doi: |
10.1007/s10800-023-01873-4 |
---|
funding: |
|
---|---|
Förderinstitution / Projekttitel: |
|
PPN (Katalog-ID): |
OLC2144162387 |
---|
LEADER | 01000naa a22002652 4500 | ||
---|---|---|---|
001 | OLC2144162387 | ||
003 | DE-627 | ||
005 | 20240118095809.0 | ||
007 | cr uuu---uuuuu | ||
008 | 240118s2023 xx |||||o 00| ||eng c | ||
024 | 7 | |a 10.1007/s10800-023-01873-4 |2 doi | |
035 | |a (DE-627)OLC2144162387 | ||
035 | |a (DE-He213)s10800-023-01873-4-e | ||
040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
041 | |a eng | ||
082 | 0 | 4 | |a 540 |q VZ |
084 | |a 35.14$jElektrochemie |2 bkl | ||
100 | 1 | |a Kaya, Sefika |e verfasserin |4 aut | |
245 | 1 | 0 | |a Enhanced hydrogen production via methanolysis and energy storage on novel poplar sawdust-based biomass-derived activated carbon catalyst |
264 | 1 | |c 2023 | |
336 | |a Text |b txt |2 rdacontent | ||
337 | |a Computermedien |b c |2 rdamedia | ||
338 | |a Online-Ressource |b cr |2 rdacarrier | ||
500 | |a © The Author(s), under exclusive licence to Springer Nature B.V. 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. | ||
520 | |a The originality of our current work is based on the use of $ H_{3} $$ PO_{4} $ functionalized waste poplar sawdust as a supercapacitor electrode material and catalyst for $ NaBH_{4} $ methanolysis reaction. $ N_{2} $ adsorption–desorption, scanning electron microscopy with energy-dispersive X-ray spectrometry (SEM–EDX), Fourier-transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) are utilized for characterization of the activated carbon (AC). In the first stage of our study, the effect of $ H_{3} $$ PO_{4} $ ratios and carbonization temperature on the hydrogen generation rate (HGR) is investigated and optimized. The optimum $ H_{3} $$ PO_{4} $ and carbonization temperature for $ NaBH_{4} $ methanolysis on AC are determined as 4:1 and 600 °C, respectively. The optimum points for the methanol concentration, $ NaBH_{4} $ concentration, reaction temperature, and catalyst amount affecting the HGR values for the methanolysis reaction on the KV4-600 catalyst under these conditions are determined as 4 ml, 1.25 wt% $ NaBH_{4} $, 60 °C, and 50 mg, respectively. Moreover, the HGR, activation energy, and the reaction completion duration under optimized reaction conditions are obtained as 19,050.00 mL $ min^{−1} $ $ g_{cat} $−1, 11.76 kJ $ mol^{−1} $, and 60 s, respectively. The performance of the KV4-600 as a supercapacitor electrode material is evaluated by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS). The specific capacitance of the KV4-600 at a specific current of 0.25 A $ g^{−1} $ is found to be 161.15 F $ g^{−1} $. KV4-600 shows satisfactory results both as supercapacitor electrode material and as catalyst for $ NaBH_{4} $ methanolysis. Graphical Abstract | ||
650 | 4 | |a Hydrogen | |
650 | 4 | |a NaBH | |
650 | 4 | |a methanolysis | |
650 | 4 | |a Supercapacitor | |
650 | 4 | |a Catalyst | |
700 | 1 | |a Saka, Ceren |4 aut | |
700 | 1 | |a Yildiz, Derya |4 aut | |
700 | 1 | |a Erol, Salim |4 aut | |
700 | 1 | |a Ulas, Berdan |4 aut | |
700 | 1 | |a Demir, Izge |4 aut | |
700 | 1 | |a Kivrak, Hilal |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Journal of applied electrochemistry |d Springer Netherlands, 1971 |g 53(2023), 8 vom: 14. März, Seite 1643-1655 |h Online-Ressource |w (DE-627)302466037 |w (DE-600)1491094-9 |w (DE-576)105357111 |x 1572-8838 |7 nnns |
773 | 1 | 8 | |g volume:53 |g year:2023 |g number:8 |g day:14 |g month:03 |g pages:1643-1655 |
856 | 4 | 0 | |u https://dx.doi.org/10.1007/s10800-023-01873-4 |z lizenzpflichtig |3 Volltext |
912 | |a GBV_USEFLAG_A | ||
912 | |a SYSFLAG_A | ||
912 | |a GBV_OLC | ||
912 | |a GBV_ILN_11 | ||
912 | |a GBV_ILN_20 | ||
912 | |a GBV_ILN_22 | ||
912 | |a GBV_ILN_23 | ||
912 | |a GBV_ILN_24 | ||
912 | |a GBV_ILN_31 | ||
912 | |a GBV_ILN_32 | ||
912 | |a GBV_ILN_39 | ||
912 | |a GBV_ILN_40 | ||
912 | |a GBV_ILN_60 | ||
912 | |a GBV_ILN_62 | ||
912 | |a GBV_ILN_63 | ||
912 | |a GBV_ILN_69 | ||
912 | |a GBV_ILN_70 | ||
912 | |a GBV_ILN_73 | ||
912 | |a GBV_ILN_74 | ||
912 | |a GBV_ILN_90 | ||
912 | |a GBV_ILN_95 | ||
912 | |a GBV_ILN_100 | ||
912 | |a GBV_ILN_101 | ||
912 | |a GBV_ILN_105 | ||
912 | |a GBV_ILN_110 | ||
912 | |a GBV_ILN_120 | ||
912 | |a GBV_ILN_138 | ||
912 | |a GBV_ILN_150 | ||
912 | |a GBV_ILN_151 | ||
912 | |a GBV_ILN_152 | ||
912 | |a GBV_ILN_161 | ||
912 | |a GBV_ILN_170 | ||
912 | |a GBV_ILN_171 | ||
912 | |a GBV_ILN_187 | ||
912 | |a GBV_ILN_206 | ||
912 | |a GBV_ILN_213 | ||
912 | |a GBV_ILN_224 | ||
912 | |a GBV_ILN_230 | ||
912 | |a GBV_ILN_250 | ||
912 | |a GBV_ILN_281 | ||
912 | |a GBV_ILN_285 | ||
912 | |a GBV_ILN_293 | ||
912 | |a GBV_ILN_370 | ||
912 | |a GBV_ILN_602 | ||
912 | |a GBV_ILN_636 | ||
912 | |a GBV_ILN_702 | ||
912 | |a GBV_ILN_2001 | ||
912 | |a GBV_ILN_2003 | ||
912 | |a GBV_ILN_2004 | ||
912 | |a GBV_ILN_2005 | ||
912 | |a GBV_ILN_2006 | ||
912 | |a GBV_ILN_2007 | ||
912 | |a GBV_ILN_2008 | ||
912 | |a GBV_ILN_2009 | ||
912 | |a GBV_ILN_2010 | ||
912 | |a GBV_ILN_2011 | ||
912 | |a GBV_ILN_2014 | ||
912 | |a GBV_ILN_2015 | ||
912 | |a GBV_ILN_2020 | ||
912 | |a GBV_ILN_2021 | ||
912 | |a GBV_ILN_2025 | ||
912 | |a GBV_ILN_2026 | ||
912 | |a GBV_ILN_2027 | ||
912 | |a GBV_ILN_2031 | ||
912 | |a GBV_ILN_2034 | ||
912 | |a GBV_ILN_2037 | ||
912 | |a GBV_ILN_2038 | ||
912 | |a GBV_ILN_2039 | ||
912 | |a GBV_ILN_2044 | ||
912 | |a GBV_ILN_2048 | ||
912 | |a GBV_ILN_2049 | ||
912 | |a GBV_ILN_2055 | ||
912 | |a GBV_ILN_2056 | ||
912 | |a GBV_ILN_2057 | ||
912 | |a GBV_ILN_2059 | ||
912 | |a GBV_ILN_2061 | ||
912 | |a GBV_ILN_2064 | ||
912 | |a GBV_ILN_2065 | ||
912 | |a GBV_ILN_2068 | ||
912 | |a GBV_ILN_2088 | ||
912 | |a GBV_ILN_2093 | ||
912 | |a GBV_ILN_2106 | ||
912 | |a GBV_ILN_2107 | ||
912 | |a GBV_ILN_2108 | ||
912 | |a GBV_ILN_2110 | ||
912 | |a GBV_ILN_2111 | ||
912 | |a GBV_ILN_2112 | ||
912 | |a GBV_ILN_2113 | ||
912 | |a GBV_ILN_2118 | ||
912 | |a GBV_ILN_2119 | ||
912 | |a GBV_ILN_2129 | ||
912 | |a GBV_ILN_2132 | ||
912 | |a GBV_ILN_2134 | ||
912 | |a GBV_ILN_2143 | ||
912 | |a GBV_ILN_2144 | ||
912 | |a GBV_ILN_2147 | ||
912 | |a GBV_ILN_2148 | ||
912 | |a GBV_ILN_2152 | ||
912 | |a GBV_ILN_2153 | ||
912 | |a GBV_ILN_2188 | ||
912 | |a GBV_ILN_2190 | ||
912 | |a GBV_ILN_2232 | ||
912 | |a GBV_ILN_2336 | ||
912 | |a GBV_ILN_2433 | ||
912 | |a GBV_ILN_2446 | ||
912 | |a GBV_ILN_2470 | ||
912 | |a GBV_ILN_2474 | ||
912 | |a GBV_ILN_2507 | ||
912 | |a GBV_ILN_2522 | ||
912 | |a GBV_ILN_2548 | ||
912 | |a GBV_ILN_4035 | ||
912 | |a GBV_ILN_4037 | ||
912 | |a GBV_ILN_4046 | ||
912 | |a GBV_ILN_4112 | ||
912 | |a GBV_ILN_4125 | ||
912 | |a GBV_ILN_4126 | ||
912 | |a GBV_ILN_4242 | ||
912 | |a GBV_ILN_4246 | ||
912 | |a GBV_ILN_4249 | ||
912 | |a GBV_ILN_4251 | ||
912 | |a GBV_ILN_4305 | ||
912 | |a GBV_ILN_4306 | ||
912 | |a GBV_ILN_4307 | ||
912 | |a GBV_ILN_4313 | ||
912 | |a GBV_ILN_4322 | ||
912 | |a GBV_ILN_4323 | ||
912 | |a GBV_ILN_4324 | ||
912 | |a GBV_ILN_4325 | ||
912 | |a GBV_ILN_4326 | ||
912 | |a GBV_ILN_4328 | ||
912 | |a GBV_ILN_4333 | ||
912 | |a GBV_ILN_4334 | ||
912 | |a GBV_ILN_4335 | ||
912 | |a GBV_ILN_4336 | ||
912 | |a GBV_ILN_4338 | ||
912 | |a GBV_ILN_4393 | ||
912 | |a GBV_ILN_4700 | ||
936 | b | k | |a 35.14$jElektrochemie |q VZ |0 106407805 |0 (DE-625)106407805 |
951 | |a AR | ||
952 | |d 53 |j 2023 |e 8 |b 14 |c 03 |h 1643-1655 |