A Cd(II) MOF based on 5-ethoxyisophthalate and 1,3-bis(4-pyridyl)propane ligands with a twofold interpenetrated crystal structure showing room temperature phosphorescence
Abstract A metal-organic framework (MOF) {[Cd(EtOIPA)(bpp)($ H_{2} $O)]·$ 2H_{2} $O} n (1) has been synthesized under basic hydrothermal conditions by using of 5-ethoxyisophthalic acid ($ EtOIPAH_{2} $) and 1,3-bis(4-pyridyl)propane (bpp) as reagents for cadmium nitrate. Compound 1 was characterized by elemental analysis, single-crystal X-ray diffraction and UV/Vis spectroscopy. In 1, the bpp ligands extend the EtOIPA-Cd chains along the ab plane to form a 2-fold 3D interpenetrating network. Compound 1 emits blue phosphorescence at room temperature with a long lifetime of 4.2 ms..
| Medienart: |
Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:78 |
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| Enthalten in: |
Zeitschrift für Naturforschung / B - 78(2023), 7-8 vom: 16. Juni, Seite 451-455 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Chen, Ying-Jun [VerfasserIn] |
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| Links: |
Volltext [lizenzpflichtig] |
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| RVK: |
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| Anmerkungen: |
© 2023 Walter de Gruyter GmbH, Berlin/Boston |
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| doi: |
10.1515/znb-2023-0019 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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OLC2143462263 |
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| 245 | 1 | 0 | |a A Cd(II) MOF based on 5-ethoxyisophthalate and 1,3-bis(4-pyridyl)propane ligands with a twofold interpenetrated crystal structure showing room temperature phosphorescence |
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| 520 | |a Abstract A metal-organic framework (MOF) {[Cd(EtOIPA)(bpp)($ H_{2} $O)]·$ 2H_{2} $O} n (1) has been synthesized under basic hydrothermal conditions by using of 5-ethoxyisophthalic acid ($ EtOIPAH_{2} $) and 1,3-bis(4-pyridyl)propane (bpp) as reagents for cadmium nitrate. Compound 1 was characterized by elemental analysis, single-crystal X-ray diffraction and UV/Vis spectroscopy. In 1, the bpp ligands extend the EtOIPA-Cd chains along the ab plane to form a 2-fold 3D interpenetrating network. Compound 1 emits blue phosphorescence at room temperature with a long lifetime of 4.2 ms. | ||
| 700 | 1 | |a Yin, Pei-Pei |4 aut | |
| 700 | 1 | |a Ren, Shu-Xian |4 aut | |
| 700 | 1 | |a Li, Zhi-Hua |4 aut | |
| 700 | 1 | |a Yang, Xiao-Gang |4 aut | |
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