Challenges and Recent Developments of Photoflow-Reversible Deactivation Radical Polymerization (RDRP)
Abstract Photo-controlled reversible-deactivation radical polymerization (photo-RDRP) has been investigated as a “green” and spatiotemporally controlling pathway for polymer synthesis. While the combination of photo-RDRP and flow chemistry has offered opportunities to increase light intensity and enable uniform light irradiation, problems associated with flow approaches still remain for photoflow-RDRP, which has hindered merging flow polymerization with other cutting-edge techniques. Herein, we summarize challenges and recent achievements in photoflow-RDRP including the development of (a) droplet/slug-flow to regulate residence time distribution, (b) mixing techniques to tailor polymer, (c) polymerization induced self-assembly, and (d) computer-aided synthesis. We hope this work will provide informative knowledge to people in related fields and stimulate novel ideas to promote polymer synthesis in both academia and industry..
| Medienart: |
Artikel |
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| Erscheinungsjahr: |
2021 |
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| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:39 |
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| Enthalten in: |
Chinese journal of polymer science - 39(2021), 9 vom: 05. Jan., Seite 1069-1083 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Zhong, Zhuo-Ran [VerfasserIn] |
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| Links: |
Volltext [lizenzpflichtig] |
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| Themen: |
Controlled radical polymerization |
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| Anmerkungen: |
© Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2021 |
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| doi: |
10.1007/s10118-021-2529-8 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
OLC2127080734 |
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| 520 | |a Abstract Photo-controlled reversible-deactivation radical polymerization (photo-RDRP) has been investigated as a “green” and spatiotemporally controlling pathway for polymer synthesis. While the combination of photo-RDRP and flow chemistry has offered opportunities to increase light intensity and enable uniform light irradiation, problems associated with flow approaches still remain for photoflow-RDRP, which has hindered merging flow polymerization with other cutting-edge techniques. Herein, we summarize challenges and recent achievements in photoflow-RDRP including the development of (a) droplet/slug-flow to regulate residence time distribution, (b) mixing techniques to tailor polymer, (c) polymerization induced self-assembly, and (d) computer-aided synthesis. We hope this work will provide informative knowledge to people in related fields and stimulate novel ideas to promote polymer synthesis in both academia and industry. | ||
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| 700 | 1 | |a Chen, Mao |4 aut | |
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