One-pot synthesis of 2-aminotetrahydrothiopyrano[4,3-b]pyran-3-carbonitrile derivatives using mesoporous $ NH_{2} $-MCM-41
Abstract A facile and general procedure is presented for the one-pot synthesis of 2-aminotetrahydrothiopyrano[4,3-b]pyran-3-carbonitrile derivatives. It is based on the three-component condensation of aliphatic, aromatic, or heterocyclic aldehydes, malononitrile, and thiopyran in the presence of mesoporous amino-functionalized MCM-41 silica in ethanol. This efficient technique has the advantage of giving 2-aminotetrahydrothiopyrano[4,3-b]pyran-3-carbonitrile derivatives using a heterogeneous mesoporous reagent in high yields, in short reaction times, and offers a simple product isolation procedure. Graphical abstract.
Medienart: |
Artikel |
---|
Erscheinungsjahr: |
2013 |
---|---|
Erschienen: |
2013 |
Enthalten in: |
Zur Gesamtaufnahme - volume:144 |
---|---|
Enthalten in: |
Monatshefte für Chemie - 144(2013), 11 vom: 12. Juli, Seite 1699-1704 |
Sprache: |
Englisch |
---|
Beteiligte Personen: |
Mirza-Aghayan, Maryam [VerfasserIn] |
---|
Links: |
Volltext [lizenzpflichtig] |
---|
Themen: |
]pyran-3-carbonitrile |
---|
RVK: |
---|
Anmerkungen: |
© Springer-Verlag Wien 2013 |
---|
doi: |
10.1007/s00706-013-1035-2 |
---|
funding: |
|
---|---|
Förderinstitution / Projekttitel: |
|
PPN (Katalog-ID): |
OLC2065553502 |
---|
LEADER | 01000caa a22002652 4500 | ||
---|---|---|---|
001 | OLC2065553502 | ||
003 | DE-627 | ||
005 | 20230513020639.0 | ||
007 | tu | ||
008 | 200820s2013 xx ||||| 00| ||eng c | ||
024 | 7 | |a 10.1007/s00706-013-1035-2 |2 doi | |
035 | |a (DE-627)OLC2065553502 | ||
035 | |a (DE-He213)s00706-013-1035-2-p | ||
040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
041 | |a eng | ||
082 | 0 | 4 | |a 540 |q VZ |
084 | |a BIODIV |q DE-30 |2 fid | ||
084 | |a VA 6100 |q VZ |2 rvk | ||
100 | 1 | |a Mirza-Aghayan, Maryam |e verfasserin |4 aut | |
245 | 1 | 0 | |a One-pot synthesis of 2-aminotetrahydrothiopyrano[4,3-b]pyran-3-carbonitrile derivatives using mesoporous $ NH_{2} $-MCM-41 |
264 | 1 | |c 2013 | |
336 | |a Text |b txt |2 rdacontent | ||
337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
338 | |a Band |b nc |2 rdacarrier | ||
500 | |a © Springer-Verlag Wien 2013 | ||
520 | |a Abstract A facile and general procedure is presented for the one-pot synthesis of 2-aminotetrahydrothiopyrano[4,3-b]pyran-3-carbonitrile derivatives. It is based on the three-component condensation of aliphatic, aromatic, or heterocyclic aldehydes, malononitrile, and thiopyran in the presence of mesoporous amino-functionalized MCM-41 silica in ethanol. This efficient technique has the advantage of giving 2-aminotetrahydrothiopyrano[4,3-b]pyran-3-carbonitrile derivatives using a heterogeneous mesoporous reagent in high yields, in short reaction times, and offers a simple product isolation procedure. Graphical abstract | ||
650 | 4 | |a 2-Aminotetrahydrothiopyrano[4,3- | |
650 | 4 | |a ]pyran-3-carbonitrile | |
650 | 4 | |a Thiopyran | |
650 | 4 | |a Amino-functionalized MCM-41 | |
650 | 4 | |a One-pot synthesis | |
700 | 1 | |a Saravani, Farhad |4 aut | |
700 | 1 | |a Tarlani, Ali Akbar |4 aut | |
700 | 1 | |a Abaee, Mohammad Saeed |4 aut | |
700 | 1 | |a Boukherroub, Rabah |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Monatshefte für Chemie |d Springer Vienna, 1968 |g 144(2013), 11 vom: 12. Juli, Seite 1699-1704 |w (DE-627)13021597X |w (DE-600)536589-2 |w (DE-576)01576205X |x 0026-9247 |7 nnns |
773 | 1 | 8 | |g volume:144 |g year:2013 |g number:11 |g day:12 |g month:07 |g pages:1699-1704 |
856 | 4 | 1 | |u https://doi.org/10.1007/s00706-013-1035-2 |z lizenzpflichtig |3 Volltext |
912 | |a GBV_USEFLAG_A | ||
912 | |a SYSFLAG_A | ||
912 | |a GBV_OLC | ||
912 | |a FID-BIODIV | ||
912 | |a SSG-OLC-CHE | ||
912 | |a SSG-OLC-PHA | ||
912 | |a SSG-OLC-DE-84 | ||
912 | |a GBV_ILN_24 | ||
912 | |a GBV_ILN_30 | ||
912 | |a GBV_ILN_70 | ||
912 | |a GBV_ILN_267 | ||
912 | |a GBV_ILN_4012 | ||
936 | r | v | |a VA 6100 |
951 | |a AR | ||
952 | |d 144 |j 2013 |e 11 |b 12 |c 07 |h 1699-1704 |