Synthesis of trinuclear $ Cu^{II} $-complex with tris(4-triphenylmethylphenoxy)-substituted hemihexaphyrazine and radioprotective properties of its water-soluble form
Abstract A condensation of 2,5-diamino-1,3,4-thiadiazole with the products of the in situ reaction of 1,2-dicyano-4-(4-triphenylmethylphenoxy)benzene with sodium alkoxides in a mixture of butanol—methanol furnished a trisubstituted ABABAB-type macroheterocycle (hemihexaphyrazine). A 3 : 1 trinuclear complex was synthesized by the reaction of the macrocycle with copper(II) acetate. The compounds obtained were characterized by IR spectroscopy, UV-vis spectroscopy, mass spectrometry, as well as by elemental analysis. Radioprotective properties of the water-soluble form of the complex were studied.
Medienart: |
Artikel |
---|
Erscheinungsjahr: |
2015 |
---|---|
Erschienen: |
2015 |
Enthalten in: |
Zur Gesamtaufnahme - volume:64 |
---|---|
Enthalten in: |
Russian chemical bulletin - 64(2015), 7 vom: Juli, Seite 1610-1615 |
Sprache: |
Englisch |
---|
Beteiligte Personen: |
Danilova, E. A. [VerfasserIn] |
---|
Links: |
Volltext [lizenzpflichtig] |
---|
Anmerkungen: |
© Springer Science+Business Media New York 2015 |
---|
doi: |
10.1007/s11172-015-1049-5 |
---|
funding: |
|
---|---|
Förderinstitution / Projekttitel: |
|
PPN (Katalog-ID): |
OLC2057713954 |
---|
LEADER | 01000caa a22002652 4500 | ||
---|---|---|---|
001 | OLC2057713954 | ||
003 | DE-627 | ||
005 | 20230511162058.0 | ||
007 | tu | ||
008 | 200820s2015 xx ||||| 00| ||eng c | ||
024 | 7 | |a 10.1007/s11172-015-1049-5 |2 doi | |
035 | |a (DE-627)OLC2057713954 | ||
035 | |a (DE-He213)s11172-015-1049-5-p | ||
040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
041 | |a eng | ||
082 | 0 | 4 | |a 540 |q VZ |
100 | 1 | |a Danilova, E. A. |e verfasserin |4 aut | |
245 | 1 | 0 | |a Synthesis of trinuclear $ Cu^{II} $-complex with tris(4-triphenylmethylphenoxy)-substituted hemihexaphyrazine and radioprotective properties of its water-soluble form |
264 | 1 | |c 2015 | |
336 | |a Text |b txt |2 rdacontent | ||
337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
338 | |a Band |b nc |2 rdacarrier | ||
500 | |a © Springer Science+Business Media New York 2015 | ||
520 | |a Abstract A condensation of 2,5-diamino-1,3,4-thiadiazole with the products of the in situ reaction of 1,2-dicyano-4-(4-triphenylmethylphenoxy)benzene with sodium alkoxides in a mixture of butanol—methanol furnished a trisubstituted ABABAB-type macroheterocycle (hemihexaphyrazine). A 3 : 1 trinuclear complex was synthesized by the reaction of the macrocycle with copper(II) acetate. The compounds obtained were characterized by IR spectroscopy, UV-vis spectroscopy, mass spectrometry, as well as by elemental analysis. Radioprotective properties of the water-soluble form of the complex were studied | ||
700 | 1 | |a Islyaikin, M. K. |4 aut | |
700 | 1 | |a Shtrygol´, S. Yu. |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Russian chemical bulletin |d Springer US, 1993 |g 64(2015), 7 vom: Juli, Seite 1610-1615 |w (DE-627)171264932 |w (DE-600)1171607-1 |w (DE-576)038728559 |x 1066-5285 |7 nnns |
773 | 1 | 8 | |g volume:64 |g year:2015 |g number:7 |g month:07 |g pages:1610-1615 |
856 | 4 | 1 | |u https://doi.org/10.1007/s11172-015-1049-5 |z lizenzpflichtig |3 Volltext |
912 | |a GBV_USEFLAG_A | ||
912 | |a SYSFLAG_A | ||
912 | |a GBV_OLC | ||
912 | |a SSG-OLC-PHA | ||
912 | |a SSG-OLC-DE-84 | ||
912 | |a GBV_ILN_70 | ||
912 | |a GBV_ILN_4012 | ||
951 | |a AR | ||
952 | |d 64 |j 2015 |e 7 |c 07 |h 1610-1615 |