Glycolipids synthesis: improved hydrazinolysis conditions for preparation of 1,2-polyunsaturated fatty acyl-β-monogalactosyl-glycerols
The investigation is related to the development of a general strategy for the synthesis of glycolipids including analogs bearing polyunsaturated fatty acids. In particular, here we report exceptionally mild and selective conditions to remove acetate protecting groups from glyceroglycolipids by hydrazinolysis. Synthetic 1,2-O-di-arachidonoyl-3-O-β-galactosyl-glycerol was used as representative of polyunsaturated β-galactosyl-di-acyl-glycerols due to its reactivity under the conditions usually employed in literature..
Medienart: |
Artikel |
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Erscheinungsjahr: |
2016 |
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Erschienen: |
2016 |
Enthalten in: |
Zur Gesamtaufnahme - volume:424 |
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Enthalten in: |
Carbohydrate research - 424(2016), Seite 21-23 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Pagano, Dario [VerfasserIn] |
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Links: |
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doi: |
10.1016/j.carres.2016.02.005 |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
OLC1974736695 |
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520 | |a The investigation is related to the development of a general strategy for the synthesis of glycolipids including analogs bearing polyunsaturated fatty acids. In particular, here we report exceptionally mild and selective conditions to remove acetate protecting groups from glyceroglycolipids by hydrazinolysis. Synthetic 1,2-O-di-arachidonoyl-3-O-β-galactosyl-glycerol was used as representative of polyunsaturated β-galactosyl-di-acyl-glycerols due to its reactivity under the conditions usually employed in literature. | ||
540 | |a Nutzungsrecht: © Elsevier Ltd | ||
540 | |a Copyright © 2016 Elsevier Ltd. All rights reserved. | ||
700 | 1 | |a Cutignano, Adele |4 oth | |
700 | 1 | |a Manzo, Emiliano |4 oth | |
700 | 1 | |a Tinto, Francesco |4 oth | |
700 | 1 | |a Fontana, Angelo |4 oth | |
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856 | 4 | 2 | |u http://www.sciencedirect.com/science/article/pii/S0008621516300246 |
856 | 4 | 2 | |u http://www.ncbi.nlm.nih.gov/pubmed/26921607 |
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