Three New Atisane Diterpenoids from Spiraea japonica
Three new atisane diterpenoids, spiratisanins A - C (1 - 3, resp.), featuring a phenylacryloxyl substituted ent-atisane skeleton, were isolated from Spiraea japonica together with two known atisine diterpene alkaloids, spiramine A (4) and spiradine F (5). The structures of these new compounds were elucidated as (5[beta],7[alpha],8[alpha],9[beta],10[alpha],12[alpha],16[beta])-16-hydroxyatisan-7-yl (2E)-3-phenylprop-2-enoate (1), (5[beta],7[alpha],8[alpha],9[beta],10[alpha],12[alpha],16[alpha])-16-hydroxyatisan-7-yl (2E)-3-phenylprop-2-enoate (2), and (5[beta],8[alpha],9[beta],10[alpha],12[alpha],16[beta])-16-hydroxyatisan-20-yl (2E)-3-phenylprop-2-enoate (3) on the basis of spectroscopic analysis..
| Medienart: |
Artikel |
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| Erscheinungsjahr: |
2016 |
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| Erschienen: |
2016 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:99 |
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| Enthalten in: |
Helvetica chimica acta - 99(2016), 3, Seite 237 |
| Sprache: |
Französisch |
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| Beteiligte Personen: |
Xiang-Dong Qin [VerfasserIn] |
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| doi: |
10.1002/hlca.201500282 |
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| 520 | |a Three new atisane diterpenoids, spiratisanins A - C (1 - 3, resp.), featuring a phenylacryloxyl substituted ent-atisane skeleton, were isolated from Spiraea japonica together with two known atisine diterpene alkaloids, spiramine A (4) and spiradine F (5). The structures of these new compounds were elucidated as (5[beta],7[alpha],8[alpha],9[beta],10[alpha],12[alpha],16[beta])-16-hydroxyatisan-7-yl (2E)-3-phenylprop-2-enoate (1), (5[beta],7[alpha],8[alpha],9[beta],10[alpha],12[alpha],16[alpha])-16-hydroxyatisan-7-yl (2E)-3-phenylprop-2-enoate (2), and (5[beta],8[alpha],9[beta],10[alpha],12[alpha],16[beta])-16-hydroxyatisan-20-yl (2E)-3-phenylprop-2-enoate (3) on the basis of spectroscopic analysis. | ||
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| 700 | 0 | |a Fei Wang |4 oth | |
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