Photoredox-catalyzed radical-radical cross coupling of ketyl radicals with unstabilized primary alkyl radicals
Herein, a novel protocol dealing with the preparation of sterically hindered alcohols has been successfully developed via radical-radical coupling reactions enabled by mild and redox-neutral photocatalysis. With alkylsilicates as the radical precursors, a range of primary alkyl radicals bearing various functional groups could couple with a range of phthalimides and activated ketones.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:60 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 60(2024), 33 vom: 18. Apr., Seite 4431-4434 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Feng, Shishen [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Revised 18.04.2024 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d4cc00620h |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM370527593 |
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| 520 | |a Herein, a novel protocol dealing with the preparation of sterically hindered alcohols has been successfully developed via radical-radical coupling reactions enabled by mild and redox-neutral photocatalysis. With alkylsilicates as the radical precursors, a range of primary alkyl radicals bearing various functional groups could couple with a range of phthalimides and activated ketones | ||
| 650 | 4 | |a Journal Article | |
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| 700 | 1 | |a Li, Yan |e verfasserin |4 aut | |
| 700 | 1 | |a Fang, Yewen |e verfasserin |4 aut | |
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