Methacrylic acid in situ modified steel converter slag/natural rubber composites : Resourceful utilization of steelmaking solid wastes
Copyright © 2024 Elsevier Ltd. All rights reserved..
As a by-product of the steelmaking industry, the large-volume production and accumulation of steel converter slag cause environmental issues such as land occupation and dust pollution. Since metal salts of unsaturated carboxylic acid can be used to reinforce rubber, this study explores the innovative application of in-situ modified steel slag, mainly comprising metal oxides, with methacrylic acid (MAA) as a rubber filler partially replacing carbon black. By etching the surface of steel slag particles with MAA, their surface roughness was increased, and the chemical bonding of metal methacrylate salt was introduced to enhance their interaction with the molecular chain of natural rubber (NR). The results showed that using the steel slag filler effectively shortened the vulcanization molding cycle of NR composites. The MAA in-situ modification effectively improved the interaction between steel slag and NR molecular chains. Meanwhile, the physical and mechanical properties, fatigue properties, and dynamic mechanical properties of the experimental group with MAA in-situ modified steel slag (MAA-in-situ-m-SS) were significantly enhanced compared with those of NR composites partially filled with unmodified slag. With the dosage of 7.5 phr or 10 phr, the above properties matched or even exceeded those of NR composites purely filled with carbon black. More importantly, partially replacing carbon black with modified steel slag reduced fossil fuel consumption and greenhouse gas emission from carbon black production. This study pioneered an effective path for the resourceful utilization of steel slag and the green development of the steelmaking and rubber industries.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2024 |
|---|---|
| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:180 |
|---|---|
| Enthalten in: |
Waste management (New York, N.Y.) - 180(2024) vom: 15. Apr., Seite 36-46 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Kong, Hao [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
12597-69-2 |
|---|
| Anmerkungen: |
Date Completed 15.04.2024 Date Revised 15.04.2024 published: Print-Electronic Citation Status MEDLINE |
|---|
| doi: |
10.1016/j.wasman.2024.03.024 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM369926412 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM369926412 | ||
| 003 | DE-627 | ||
| 005 | 20240415233457.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 240320s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.wasman.2024.03.024 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1376.xml |
| 035 | |a (DE-627)NLM369926412 | ||
| 035 | |a (NLM)38503032 | ||
| 035 | |a (PII)S0956-053X(24)00171-5 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Kong, Hao |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Methacrylic acid in situ modified steel converter slag/natural rubber composites |b Resourceful utilization of steelmaking solid wastes |
| 264 | 1 | |c 2024 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 15.04.2024 | ||
| 500 | |a Date Revised 15.04.2024 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a Copyright © 2024 Elsevier Ltd. All rights reserved. | ||
| 520 | |a As a by-product of the steelmaking industry, the large-volume production and accumulation of steel converter slag cause environmental issues such as land occupation and dust pollution. Since metal salts of unsaturated carboxylic acid can be used to reinforce rubber, this study explores the innovative application of in-situ modified steel slag, mainly comprising metal oxides, with methacrylic acid (MAA) as a rubber filler partially replacing carbon black. By etching the surface of steel slag particles with MAA, their surface roughness was increased, and the chemical bonding of metal methacrylate salt was introduced to enhance their interaction with the molecular chain of natural rubber (NR). The results showed that using the steel slag filler effectively shortened the vulcanization molding cycle of NR composites. The MAA in-situ modification effectively improved the interaction between steel slag and NR molecular chains. Meanwhile, the physical and mechanical properties, fatigue properties, and dynamic mechanical properties of the experimental group with MAA in-situ modified steel slag (MAA-in-situ-m-SS) were significantly enhanced compared with those of NR composites partially filled with unmodified slag. With the dosage of 7.5 phr or 10 phr, the above properties matched or even exceeded those of NR composites purely filled with carbon black. More importantly, partially replacing carbon black with modified steel slag reduced fossil fuel consumption and greenhouse gas emission from carbon black production. This study pioneered an effective path for the resourceful utilization of steel slag and the green development of the steelmaking and rubber industries | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Filler | |
| 650 | 4 | |a In situ modification | |
| 650 | 4 | |a Methacrylic acid | |
| 650 | 4 | |a Natural rubber | |
| 650 | 4 | |a Steel slag | |
| 650 | 7 | |a Rubber |2 NLM | |
| 650 | 7 | |a 9006-04-6 |2 NLM | |
| 650 | 7 | |a methacrylic acid |2 NLM | |
| 650 | 7 | |a 1CS02G8656 |2 NLM | |
| 650 | 7 | |a Solid Waste |2 NLM | |
| 650 | 7 | |a Steel |2 NLM | |
| 650 | 7 | |a 12597-69-2 |2 NLM | |
| 650 | 7 | |a Soot |2 NLM | |
| 650 | 7 | |a Industrial Waste |2 NLM | |
| 650 | 7 | |a Metals |2 NLM | |
| 650 | 7 | |a Methacrylates |2 NLM | |
| 700 | 1 | |a Luo, Kangyu |e verfasserin |4 aut | |
| 700 | 1 | |a Yong, Zhanfu |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Waste management (New York, N.Y.) |d 1999 |g 180(2024) vom: 15. Apr., Seite 36-46 |w (DE-627)NLM098197061 |x 1879-2456 |7 nnns |
| 773 | 1 | 8 | |g volume:180 |g year:2024 |g day:15 |g month:04 |g pages:36-46 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1016/j.wasman.2024.03.024 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 180 |j 2024 |b 15 |c 04 |h 36-46 | ||