Ratiometric Fluorescence Optical Fiber Enabling Operando Temperature Monitoring in Pouch-Type Battery

© 2024 Wiley-VCH GmbH..

Thermal characteristics are essential for improving the performance and monitoring the status of Li-ion batteries (LIBs). However, it is a challenge to design efficient and facile sensing materials for the detection of the in situ temperature of a working LIB. Herein, a ratiometric fluorescence optical fiber is developed and real-time temperature monitoring is performed with a measurement accuracy of 0.12 °C, and the feasibility based on this polymer optical fiber composed of NaLaTi2 O6 :Yb/Er phosphors is verified in a pouch-type battery. During the charging and discharging cycles, the in situ temperature is instantaneously conveyed, revealing the internal situation of LIBs. This article further dwells on the thermal characteristics in constant current (CC)/constant voltage charging and CC discharging processes at different C-rates and the battery failure when operated at low temperatures (0 °C). This work demonstrates an innovative strategy for operando solitary temperature monitoring conducted by ratiometric fluorescence optical fiber.

Medienart:

E-Artikel

Erscheinungsjahr:

2024

Erschienen:

2024

Enthalten in:

Zur Gesamtaufnahme - year:2024

Enthalten in:

Advanced materials (Deerfield Beach, Fla.) - (2024) vom: 13. März, Seite e2401057

Sprache:

Englisch

Beteiligte Personen:

Wang, Yuzhen [VerfasserIn]
Zhang, Qimeng [VerfasserIn]
Yang, Chenghao [VerfasserIn]
Xia, Zhiguo [VerfasserIn]

Links:

Volltext

Themen:

Fluorescence optical fiber
Journal Article
Operando temperature monitoring
Ratiometric thermometry

Anmerkungen:

Date Revised 19.03.2024

published: Print-Electronic

Citation Status Publisher

doi:

10.1002/adma.202401057

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM369695526