Adsorption removal of cationic dyes from wastewater using the corn straw modified with diethylenetriaminepentacetic acid ligand

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Taking the thiazide cationic dye methylene blue (MB), triphenylmethane cationic dye crystal violet (CV), monoazo cationic dye cationic red 46 (R-46), and polycarboxycyanine cationic dye cationic rosé FG (P-FG) as the research objects, the adsorption behaviors of a self-made corn straw modified adsorbent HQ-DTPA-I for the dyes were investigated in depth. Under optimized conditions, HQ-DTPA-I can quickly adsorb most dyes within 3 min and reach equilibrium adsorption in 15-20 min. The removal rates of HQ-DTPA-I to MB, CV, R-46 and AP-FG can reach 95.28 %, 99.78 %, 99.28 % and 98.53 %, respectively. It also has good anti-interference ability for common ions present in most actual dye wastewater. For six consecutive adsorption-desorption cycles, the adsorption performance of HQ-DTPA-I can still reach 80.17 %, 81.61 %, 90.77 % and 83.48 % of the initial adsorption capacity, indicating good recovery performance. Based on Gaussian density functional theory to calculate its surface potential energy, it is found that the adsorption mechanism of HQ-DTPA-I for the cationic dyes is mainly due to the electrostatic interaction between the carboxyl groups in ligand DTPA and amino groups in dye molecules.

Medienart:

E-Artikel

Erscheinungsjahr:

2024

Erschienen:

2024

Enthalten in:

Zur Gesamtaufnahme - volume:1720

Enthalten in:

Journal of chromatography. A - 1720(2024) vom: 12. Apr., Seite 464781

Sprache:

Englisch

Beteiligte Personen:

Hu, Hongbin [VerfasserIn]
Zhao, Lang [VerfasserIn]
Yao, Lu [VerfasserIn]
He, Min [VerfasserIn]
Lv, Yuwei [VerfasserIn]
Li, Rong [VerfasserIn]

Links:

Volltext

Themen:

7A314HQM0I
Adsorption behavior
Cationic dye
Cations
Coloring Agents
Corn straw
Density functional theory
Diethylenetriaminepentacetic acid
Gentian Violet
J4Z741D6O5
Journal Article
Ligands
Methylene Blue
Pentetic Acid
T42P99266K
Wastewater
Water Pollutants, Chemical

Anmerkungen:

Date Completed 01.04.2024

Date Revised 01.04.2024

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1016/j.chroma.2024.464781

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM369610164