Synthesis of easily-modified and useful dibenzo-[b,d]azepines by palladium(II)-catalyzed cyclization/addition with a green solvent
A novel strategy in which palladium(II)-catalyzed tandem cyclization is used to obtain N-heterocyclic architectures containing a seven-membered ring has been developed and used to synthesize a series of derivatives. The reaction uses an eco-friendly mixed solvent (water : EtOH = 2 : 1) instead of DMSO and maintains a high yield (91%). Its potential application value and reaction mechanism have also been explored.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:60 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 60(2024), 26 vom: 26. März, Seite 3587-3590 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Cheng, Hua [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Revised 26.03.2024 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d3cc06321f |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM369600444 |
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| 100 | 1 | |a Cheng, Hua |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Synthesis of easily-modified and useful dibenzo-[b,d]azepines by palladium(II)-catalyzed cyclization/addition with a green solvent |
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| 520 | |a A novel strategy in which palladium(II)-catalyzed tandem cyclization is used to obtain N-heterocyclic architectures containing a seven-membered ring has been developed and used to synthesize a series of derivatives. The reaction uses an eco-friendly mixed solvent (water : EtOH = 2 : 1) instead of DMSO and maintains a high yield (91%). Its potential application value and reaction mechanism have also been explored | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Liu, Rongqi |e verfasserin |4 aut | |
| 700 | 1 | |a Fang, Shengyang |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Zixiang |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Denggao |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Xi |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Wenfei |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Huixin |e verfasserin |4 aut | |
| 700 | 1 | |a Kang, Leyi |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Juan |e verfasserin |4 aut | |
| 700 | 1 | |a Xu, Yulong |e verfasserin |4 aut | |
| 700 | 1 | |a Song, Shaoli |e verfasserin |4 aut | |
| 700 | 1 | |a Shao, Liming |e verfasserin |4 aut | |
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