Porphyrin(2.1.2.1) organopalladium complexes as efficient singlet oxygen sensitizers
Four new non-planar and non-aromatic porphyrin organopalladium complexes were synthesized. Conformational structures and optical and electronic properties of the obtained organopalladium complexes containing meso-substituted phenyl, p-tert-butylphenyl, or pentafluorophenyl groups were fully investigated. These complexes showed potent capacity for singlet oxygen (1O2) generation under blue-light irradiation, and the 1O2 quantum yields were in the range of 41%-56%, which were comparable to that of Ru(bpy)3Cl2 (57%), and such potency made these organopalladium complexes potential 1O2 photo sensitizers for photodynamic therapy.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:53 |
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| Enthalten in: |
Dalton transactions (Cambridge, England : 2003) - 53(2024), 13 vom: 26. März, Seite 5979-5984 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Lv, Xiaojuan [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Revised 26.03.2024 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d4dt00143e |
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| funding: |
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| Förderinstitution / Projekttitel: |
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NLM369551079 |
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| 245 | 1 | 0 | |a Porphyrin(2.1.2.1) organopalladium complexes as efficient singlet oxygen sensitizers |
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| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a Four new non-planar and non-aromatic porphyrin organopalladium complexes were synthesized. Conformational structures and optical and electronic properties of the obtained organopalladium complexes containing meso-substituted phenyl, p-tert-butylphenyl, or pentafluorophenyl groups were fully investigated. These complexes showed potent capacity for singlet oxygen (1O2) generation under blue-light irradiation, and the 1O2 quantum yields were in the range of 41%-56%, which were comparable to that of Ru(bpy)3Cl2 (57%), and such potency made these organopalladium complexes potential 1O2 photo sensitizers for photodynamic therapy | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Dong, Yuting |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Jinrong |e verfasserin |4 aut | |
| 700 | 1 | |a Jiang, Tao |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Feng |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Tao |e verfasserin |4 aut | |
| 700 | 1 | |a Qiu, Fengxian |e verfasserin |4 aut | |
| 700 | 1 | |a Xue, Songlin |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Dalton transactions (Cambridge, England : 2003) |d 2004 |g 53(2024), 13 vom: 26. März, Seite 5979-5984 |w (DE-627)NLM149339739 |x 1477-9234 |7 nnns |
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