Preparation of phosphorus-doped chitosan derivative and its applications in polylactic acid : Crystallization, flame retardancy, anti-dripping and mechanical properties
Copyright © 2024 Elsevier B.V. All rights reserved..
The topic of biobased flame-retardant PLA has always been of great interest. In our study, we successfully synthesized a phosphorus-containing chitosan derivative (PCS) and combined it with aluminum hypophosphate (AP) to create an effective flame-retardant PLA system. PCS acted as an enhancer, enhancing the thermal performance, crystallinity, and toughness of PLA/AP. Compared to PLA modified with 12 wt% AP achieving UL-94 V-2 level and 24.3 % of limited oxygen index, PLA containing 3 wt% PCS and 9 wt% AP achieved UL-94 V-0 level and limited oxygen index of 28 %. The system testing studies such as CCT, Raman, XPS, and TG-IR results indicated that PLA/AP/PCS exhibited a dual flame-retardant mechanism of condensed and gas phases.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:265 |
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| Enthalten in: |
International journal of biological macromolecules - 265(2024), Pt 1 vom: 20. Apr., Seite 130648 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Liu, Liyan [VerfasserIn] |
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| Links: |
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| Themen: |
27YLU75U4W |
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| Anmerkungen: |
Date Completed 17.04.2024 Date Revised 17.04.2024 published: Print-Electronic Citation Status MEDLINE |
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| doi: |
10.1016/j.ijbiomac.2024.130648 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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NLM369503678 |
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| 245 | 1 | 0 | |a Preparation of phosphorus-doped chitosan derivative and its applications in polylactic acid |b Crystallization, flame retardancy, anti-dripping and mechanical properties |
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| 500 | |a Date Revised 17.04.2024 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a Copyright © 2024 Elsevier B.V. All rights reserved. | ||
| 520 | |a The topic of biobased flame-retardant PLA has always been of great interest. In our study, we successfully synthesized a phosphorus-containing chitosan derivative (PCS) and combined it with aluminum hypophosphate (AP) to create an effective flame-retardant PLA system. PCS acted as an enhancer, enhancing the thermal performance, crystallinity, and toughness of PLA/AP. Compared to PLA modified with 12 wt% AP achieving UL-94 V-2 level and 24.3 % of limited oxygen index, PLA containing 3 wt% PCS and 9 wt% AP achieved UL-94 V-0 level and limited oxygen index of 28 %. The system testing studies such as CCT, Raman, XPS, and TG-IR results indicated that PLA/AP/PCS exhibited a dual flame-retardant mechanism of condensed and gas phases | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Chitosan | |
| 650 | 4 | |a Flame retardancy | |
| 650 | 4 | |a Mechanical properties | |
| 650 | 4 | |a Polylactic acid | |
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| 650 | 7 | |a Phosphorus |2 NLM | |
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| 700 | 1 | |a Wang, Yadong |e verfasserin |4 aut | |
| 700 | 1 | |a Cheng, Chunzu |e verfasserin |4 aut | |
| 700 | 1 | |a Lyu, Shisheng |e verfasserin |4 aut | |
| 700 | 1 | |a Zhu, Zongmin |e verfasserin |4 aut | |
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