Adsorption of humic acid from different organic solid waste compost to phenanthrene, is fluorescence excitation or quenching?

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Humic acid (HA) from different organic solid waste (OSW) compost has been shown good adsorption properties for phenanthrene. However, the raw material of HA can affect its structure, resulting in differences in adsorption capacity. Therefore, this study focused on the adsorption characteristics of phenanthrene by HA from different OSW compost. In this work, chicken manure (CM), rice straw (RS) and lawn waste (LW) were selected as sources of composted HA. The adsorption mechanism of HA from different OSW compost were revealed through analytical techniques including three-dimensional fluorescence spectroscopy (EEM), two-dimensional correlation spectroscopy (2DCOS), and Fourier-transform infrared spectroscopy (FTIR). The results suggested that HA from LW compost had a better adsorption affinity for phenanthrene because of its more complex fluorescent component, where C1 as a simple component determined the adsorption process specifically. Furthermore, after HA from LW compost adsorbed phenanthrene, the increase in aromatic -COOH and -NH was the main reason for fluorescence quenching. These results indicated that HA from LW compost had better adsorption effect for phenanthrene. The results of this study were expected to provide a selection scheme for the control of phenanthrene pollution and environmental remediation.

Medienart:

E-Artikel

Erscheinungsjahr:

2024

Erschienen:

2024

Enthalten in:

Zur Gesamtaufnahme - volume:347

Enthalten in:

Environmental pollution (Barking, Essex : 1987) - 347(2024) vom: 15. Apr., Seite 123712

Sprache:

Englisch

Beteiligte Personen:

Su, Xinya [VerfasserIn]
Zhang, Ruju [VerfasserIn]
Cao, Huan [VerfasserIn]
Mu, Daichen [VerfasserIn]
Wang, Liqin [VerfasserIn]
Song, Caihong [VerfasserIn]
Wei, Zimin [VerfasserIn]
Zhao, Yue [VerfasserIn]

Links:

Volltext

Themen:

448J8E5BST
Compost
Fluorescent components
Humic Substances
Humic acid
Journal Article
Phenanthrene
Phenanthrenes
Soil
Solid Waste
Spectroscopical analysis

Anmerkungen:

Date Completed 08.04.2024

Date Revised 08.04.2024

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1016/j.envpol.2024.123712

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM369503252