Research and application of active species based on high-valent iron for the degradation of pollutants : A critical review

Copyright © 2024 Elsevier B.V. All rights reserved..

Fe(VI), as a new green treatment agent, has two indispensable processes in water treatment: coagulation and oxidation. Fe(VI) has a strong oxidation ability. The intermediate iron species (Fe(V) and Fe(IV)) and reactive radical species (H2O2, •OH, and O2•-) produced by decomposition and reduction reaction have strong oxidation ability, in addition, the hydrolyzed product formed in situ with core (γ-Fe2O3)-shell (γ-FeOOH) structure also has good coagulation effect. Because Fe(VI) is easy to decompose and challenging to preserve, it limits the application and sometimes significantly reduces the subsequent processing effect. How to make Fe(VI) more efficient use is a hot spot in current research. This article summarizes the distribution of active substances during the hydrolysis of Fe(VI), distinguish the differences mechanisms in the similar regulation methods, reviews the current preparation methods of Fe(VI), and finally reviews the applications of Fe(VI) in the field of environmental remediation.

Medienart:

E-Artikel

Erscheinungsjahr:

2024

Erschienen:

2024

Enthalten in:

Zur Gesamtaufnahme - volume:924

Enthalten in:

The Science of the total environment - 924(2024) vom: 10. Apr., Seite 171430

Sprache:

Englisch

Beteiligte Personen:

Liu, Yang [VerfasserIn]
Yuan, Yang [VerfasserIn]
Wang, Yue [VerfasserIn]
Ngo, Huu Hao [VerfasserIn]
Wang, Jie [VerfasserIn]

Links:

Volltext

Themen:

Environmental remediation
Ferrate(VI)
High-valent iron intermediates
Hydrolysis products
Journal Article
Review

Anmerkungen:

Date Revised 02.04.2024

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1016/j.scitotenv.2024.171430

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM369481860