Light Enables the Cathodic Interface Reaction Reversibility in Solid-State Lithium-Oxygen Batteries
© 2024 Wiley‐VCH GmbH..
Limited triple-phase boundaries arising from the accumulation of solid discharge product(s) in solid-state cathodes (SSCs) pose a challenge to high-property solid-state lithium-oxygen batteries (SSLOBs). Light-assisted SSLOBs have been gradually explored as an ingenious system; however, the fundamental mechanisms of the SSCs interface behavior remain unclear. Here, we discovered that light assistance can enhance the fast inner-sphere charge transfer in SSCs and regulate the discharge products with spherical particles generated via the surface growth model. Moreover, the high photoelectron excitation and transportation capabilities of SSCs can retard cathodic catalytic decay by avoiding structural degradation of the cathode with a reduced charge voltage. The light-induced SSLOBs exhibited excellent stability (170 cycles) with a low discharge-charge polarization overpotential (0.27 V). Furthermore, transparent SSLOBs with exceptional flexibility, mechanical stability, and multiform shapes were fabricated for theory-to-practical applications in sunlight-induced batteries. Our study opens new opportunities for the introduction of solar energy into energy storage systems.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:63 |
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| Enthalten in: |
Angewandte Chemie (International ed. in English) - 63(2024), 17 vom: 22. Apr., Seite e202319529 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ren, Liping [VerfasserIn] |
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| Links: |
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| Themen: |
Electrochemical behavior |
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| Anmerkungen: |
Date Revised 15.04.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1002/anie.202319529 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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NLM369335635 |
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| 520 | |a Limited triple-phase boundaries arising from the accumulation of solid discharge product(s) in solid-state cathodes (SSCs) pose a challenge to high-property solid-state lithium-oxygen batteries (SSLOBs). Light-assisted SSLOBs have been gradually explored as an ingenious system; however, the fundamental mechanisms of the SSCs interface behavior remain unclear. Here, we discovered that light assistance can enhance the fast inner-sphere charge transfer in SSCs and regulate the discharge products with spherical particles generated via the surface growth model. Moreover, the high photoelectron excitation and transportation capabilities of SSCs can retard cathodic catalytic decay by avoiding structural degradation of the cathode with a reduced charge voltage. The light-induced SSLOBs exhibited excellent stability (170 cycles) with a low discharge-charge polarization overpotential (0.27 V). Furthermore, transparent SSLOBs with exceptional flexibility, mechanical stability, and multiform shapes were fabricated for theory-to-practical applications in sunlight-induced batteries. Our study opens new opportunities for the introduction of solar energy into energy storage systems | ||
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| 650 | 4 | |a light assistance | |
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| 650 | 4 | |a solid-state lithium-oxygen battery | |
| 700 | 1 | |a Zheng, Ming |e verfasserin |4 aut | |
| 700 | 1 | |a Kong, Fanpeng |e verfasserin |4 aut | |
| 700 | 1 | |a Yu, Zhenjiang |e verfasserin |4 aut | |
| 700 | 1 | |a Sun, Nan |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Menglu |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Qingsong |e verfasserin |4 aut | |
| 700 | 1 | |a Song, Yajie |e verfasserin |4 aut | |
| 700 | 1 | |a Dong, Jidong |e verfasserin |4 aut | |
| 700 | 1 | |a Qiao, Jinli |e verfasserin |4 aut | |
| 700 | 1 | |a Xu, Nengneng |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Jian |e verfasserin |4 aut | |
| 700 | 1 | |a Lou, Shuaifeng |e verfasserin |4 aut | |
| 700 | 1 | |a Jiang, Zaixing |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Jiajun |e verfasserin |4 aut | |
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