MOFsPOMs-derived bimetallic oxide Fe2(MoO4)3 nanoparticles for sensitive colorimetric detection of salicylic acid in aspirin

© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature..

A colorimetric sensing method for salicylic acid (SA) was developed by designing and fabricating bimetallic oxide nanozymes. Firstly, by calcinating MIL-100(Fe)PMo12 (MOFs@POMs) at different temperature, Fe2(MoO4)3-Ts (T = 400℃, 500℃, 600℃, 700℃) nanoparticles (NPs) were successfully prepared. Secondly, by evaluating the peroxidase-like activities, Fe2(MoO4)3-600 NPs shows the best peroxidase-like activity attributed to the Fenton-like effect and the synergistic coupling interaction between Mo and Fe. Finally, based on the specific complexation between SA and Fe3+, a sensitive colorimetric sensor for SA was established, which exhibits superior selectivity and interference with a detection limit of 0.11 μM and a linear range of 10 to 100 μM, the lowest LOD for SA to date, to the best of our knowledge.

Medienart:

E-Artikel

Erscheinungsjahr:

2024

Erschienen:

2024

Enthalten in:

Zur Gesamtaufnahme - volume:191

Enthalten in:

Mikrochimica acta - 191(2024), 4 vom: 05. März, Seite 178

Sprache:

Englisch

Beteiligte Personen:

Han, Hong [VerfasserIn]
Ji, Yuhan [VerfasserIn]
Zhao, Xin [VerfasserIn]
Yin, Ling [VerfasserIn]
Liu, Xiangyi [VerfasserIn]
Sha, Jingquan [VerfasserIn]

Links:

Volltext

Themen:

Absorbance measurment
Aspirin
Complexation
Fe2(MoO4)3 NPs
Journal Article
Salicylic acid

Anmerkungen:

Date Revised 08.04.2024

published: Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1007/s00604-024-06261-z

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM369334434