Ligand engineering to achieve synergistic properties in a 2D bilayer supertetrahedral chalcogenide cluster-based assembled material
Incorporating functional organic linkers into supertetrahedral chalcogenolate cluster-based materials is an effective synthetic strategy to expand structural diversity and generate tunable optical and photoelectric properties arising from synergistic effects. Herein, a mixed ligand engineering approach was adopted to design a supertetrahedral cluster-based assembled material [(Cd6Ag4(SPh)16(TPPA)(BPE)0.5)·2DMF]n (denoted as SCCAM-3) with a 2D bilayer architecture and broader visible-light absorption. Interestingly, SCCAM-3 demonstrates a long-lived afterglow at 83 K and efficient photocatalytic activity for degrading tetracycline in water.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:60 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 60(2024), 24 vom: 19. März, Seite 3279-3282 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Li, Yan-Ling [VerfasserIn] |
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| Links: |
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| Anmerkungen: |
Date Revised 19.03.2024 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d3cc05726g |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM369109147 |
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| 520 | |a Incorporating functional organic linkers into supertetrahedral chalcogenolate cluster-based materials is an effective synthetic strategy to expand structural diversity and generate tunable optical and photoelectric properties arising from synergistic effects. Herein, a mixed ligand engineering approach was adopted to design a supertetrahedral cluster-based assembled material [(Cd6Ag4(SPh)16(TPPA)(BPE)0.5)·2DMF]n (denoted as SCCAM-3) with a 2D bilayer architecture and broader visible-light absorption. Interestingly, SCCAM-3 demonstrates a long-lived afterglow at 83 K and efficient photocatalytic activity for degrading tetracycline in water | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Liu, Yu-Dong |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Wei-Li |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Fu-An |e verfasserin |4 aut | |
| 700 | 1 | |a Feng, Yun-Xiao |e verfasserin |4 aut | |
| 700 | 1 | |a Luo, Xiao-Qiang |e verfasserin |4 aut | |
| 700 | 1 | |a Han, Yong-Jun |e verfasserin |4 aut | |
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