Modular Synthesis of Improbable Rotaxanes with All-Benzene Scaffolds
© 2024 Wiley‐VCH GmbH..
"Improbable" rotaxanes consisting of interlocked conjugated components represent non-trivial synthetic targets, not to mention those with all-benzene scaffolds. Herein, a modular synthetic strategy has been established using an isolable azo-linked pre-rotaxane as the core module, in which the azo group functions as a tracelessly removable template to direct mechanical bond formations. Through versatile connections of the pre-rotaxane and other customizable modules, [2]- and [3]rotaxanes derived from all-benzene scaffolds have been accomplished, demonstrating the utility and potential of the synthetic design for all-benzene interlocked supramolecules.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:63 |
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| Enthalten in: |
Angewandte Chemie (International ed. in English) - 63(2024), 18 vom: 24. Apr., Seite e202401838 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Bu, An [VerfasserIn] |
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| Links: |
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| Themen: |
All-benzene scaffolds |
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| Anmerkungen: |
Date Revised 18.04.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1002/anie.202401838 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| 520 | |a "Improbable" rotaxanes consisting of interlocked conjugated components represent non-trivial synthetic targets, not to mention those with all-benzene scaffolds. Herein, a modular synthetic strategy has been established using an isolable azo-linked pre-rotaxane as the core module, in which the azo group functions as a tracelessly removable template to direct mechanical bond formations. Through versatile connections of the pre-rotaxane and other customizable modules, [2]- and [3]rotaxanes derived from all-benzene scaffolds have been accomplished, demonstrating the utility and potential of the synthetic design for all-benzene interlocked supramolecules | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a all-benzene scaffolds | |
| 650 | 4 | |a azobenzene | |
| 650 | 4 | |a cycloparaphenylenes | |
| 650 | 4 | |a modular synthesis | |
| 650 | 4 | |a rotaxanes | |
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| 700 | 1 | |a Chen, Yiming |e verfasserin |4 aut | |
| 700 | 1 | |a Xiao, Hongyan |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Hongwei |e verfasserin |4 aut | |
| 700 | 1 | |a Tung, Chen-Ho |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Li-Zhu |e verfasserin |4 aut | |
| 700 | 1 | |a Cong, Huan |e verfasserin |4 aut | |
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