Construction and mechanism analysis of flame-retardant, energy-storage and transparent bio-based composites based on natural cellulose template

Copyright © 2024. Published by Elsevier B.V..

With the proposal of sustainable development strategy, bio-based energy storage transparent wood (TW) has shown broad application value in green buildings, cold chain transportation, and optoelectronic device fields. However, its application in most fields is limited due to its own flammability. In this study, epoxy resin, triethyl phosphate (TEP) and polyethylene glycol (PEG) were introduced into delignified balsa wood template by vacuum pressure impregnation, and bio-based TW/PEG/TEP integrating flame retardant, high strength and phase-change energy-storage performance was prepared. TW/PEG composites have no leakage during phase change process and their transparency is up to 95 %. Compared with TW/PEG, the shielding effect of char layer and the inhibition effect in condensed and gas phase significantly decrease the total heat release of TW/PEG/TEP. TW/PEG/TEP biocomposites still maintained a high enthalpy of phase change and a low peak melting temperature, which was conducive to its application around the area of low temperature phase change energy storage. In addition, the tensile strength of TW/PEG/TEP was nearly 4 times higher than that of DW, and its toughness was obviously enhanced. TW/PEG/TEP biocomposites conformed to the current concept of energy-saving and green development. It has the potential to replace traditional petrochemical-based materials and shows excellent application prospects in emerging fields.

Medienart:

E-Artikel

Erscheinungsjahr:

2024

Erschienen:

2024

Enthalten in:

Zur Gesamtaufnahme - volume:263

Enthalten in:

International journal of biological macromolecules - 263(2024), Pt 1 vom: 29. März, Seite 130317

Sprache:

Englisch

Beteiligte Personen:

Li, Mixue [VerfasserIn]
Li, Xu [VerfasserIn]
Xu, Kai [VerfasserIn]
Qin, Ao [VerfasserIn]
Yan, Chentao [VerfasserIn]
Xu, Yue [VerfasserIn]
Shan, Depeng [VerfasserIn]
Wang, Jinlong [VerfasserIn]
Xu, Miaojun [VerfasserIn]
Li, Xiaoli [VerfasserIn]
Li, Bin [VerfasserIn]
Liu, Lubin [VerfasserIn]

Links:

Volltext

Themen:

3WJQ0SDW1A
9004-34-6
Cellulose
Fire safety
Flame Retardants
Journal Article
Organophosphates
Phase change energy storage
Polyethylene Glycols
QIH4K96K7J
Transparent wood
Triethyl phosphate

Anmerkungen:

Date Completed 27.03.2024

Date Revised 27.03.2024

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1016/j.ijbiomac.2024.130317

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM368776220