Implementing a Doping Approach for Poly(methyl methacrylate) Recycling in a Circular Economy
To mitigate pollution by plastic waste, it is paramount to develop polymers with efficient recyclability while retaining desirable physical properties. A recyclable poly(methyl methacrylate) (PMMA) is synthesized by incorporating a minimal amount of an α-methylstyrene (AMS) analogue into the polymer structure. This P(MMA-co-AMS) copolymer preserves the essential mechanical strength and optical clarity of PMMA, vital for its wide-ranging applications in various commercial and high-tech industries. Doping with AMS significantly enhances the thermal, catalyst-free depolymerization efficiency of PMMA, facilitating the recovery of methyl methacrylate (MMA) with high yield and purity at temperatures ranging from 150 to 210 °C, nearly 250 K lower than current industrial standards. Furthermore, the low recovery temperature permits the isolation of pure MMA from a mixture of assorted common plastics.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2024 |
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Erschienen: |
2024 |
Enthalten in: |
Zur Gesamtaufnahme - volume:146 |
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Enthalten in: |
Journal of the American Chemical Society - 146(2024), 9 vom: 06. März, Seite 5786-5792 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Chin, Mason T [VerfasserIn] |
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Date Revised 10.03.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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doi: |
10.1021/jacs.3c13223 |
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PPN (Katalog-ID): |
NLM36872073X |
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