Hypervalent Iodine Compounds in Carbohydrate Chemistry : Glycosylation, Functionalization and Oxidation
© 2024 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH..
This mini review article provides an overview on the use of hypervalent iodine compounds (HICs) in carbohydrate synthesis, focusing on their chemistry and recent applications. HICs are similar to transition metals in their reactivity but have the added benefit of being environmentally benign, and are therefore commonly used as selective oxidants and eco-friendly reagents in organic synthesis. Herein, we summarize various synthetic uses of hypervalent iodine reagents in reactions such as glycosylation, oxidations, functionalization, and C-C bond-forming reactions. The goal of this review is to illustrate the advantages and versatility of using HICs as an environmentally sustainable alternative to heavy metals in carbohydrate chemistry.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - year:2024 |
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| Enthalten in: |
Chemistry (Weinheim an der Bergstrasse, Germany) - (2024) vom: 13. Feb., Seite e202400087 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Mahanti, Mukul [VerfasserIn] |
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| Links: |
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| Themen: |
Anomeric |
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| Anmerkungen: |
Date Revised 18.03.2024 published: Print-Electronic Citation Status Publisher |
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| doi: |
10.1002/chem.202400087 |
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NLM368400859 |
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| 520 | |a © 2024 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH. | ||
| 520 | |a This mini review article provides an overview on the use of hypervalent iodine compounds (HICs) in carbohydrate synthesis, focusing on their chemistry and recent applications. HICs are similar to transition metals in their reactivity but have the added benefit of being environmentally benign, and are therefore commonly used as selective oxidants and eco-friendly reagents in organic synthesis. Herein, we summarize various synthetic uses of hypervalent iodine reagents in reactions such as glycosylation, oxidations, functionalization, and C-C bond-forming reactions. The goal of this review is to illustrate the advantages and versatility of using HICs as an environmentally sustainable alternative to heavy metals in carbohydrate chemistry | ||
| 650 | 4 | |a Journal Article | |
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| 650 | 4 | |a Hypervalent Iodinium Compounds (HIC) | |
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| 700 | 1 | |a Wallentin, Carl Johan |e verfasserin |4 aut | |
| 700 | 1 | |a Galan, M Carmen |e verfasserin |4 aut | |
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