C(sp2)-H selenylation of substituted benzo[4,5]imidazo[2,1-b]thiazoles using phenyliodine(iii)bis(trifluoroacetate) as a mediator
This journal is © The Royal Society of Chemistry..
Herein, an expeditious metal-free regioselective C-H selenylation of substituted benzo[4,5]imidazo[2,1-b]thiazole derivatives was devised to synthesize structurally orchestrated selenoethers with good to excellent yields. This PIFA [bis(trifluoroacetoxy)iodobenzene]-mediated protocol operates under mild conditions and offers broad functional group tolerance. In-depth mechanistic investigation supports the involvement of radical pathways. Furthermore, the synthetic utility of this methodology is portrayed through gram-scale synthesis.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:14 |
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| Enthalten in: |
RSC advances - 14(2024), 7 vom: 31. Jan., Seite 4462-4470 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ghosh, Prasanjit [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Revised 06.02.2024 published: Electronic-eCollection Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d4ra00057a |
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| funding: |
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| Förderinstitution / Projekttitel: |
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NLM368019357 |
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| 520 | |a This journal is © The Royal Society of Chemistry. | ||
| 520 | |a Herein, an expeditious metal-free regioselective C-H selenylation of substituted benzo[4,5]imidazo[2,1-b]thiazole derivatives was devised to synthesize structurally orchestrated selenoethers with good to excellent yields. This PIFA [bis(trifluoroacetoxy)iodobenzene]-mediated protocol operates under mild conditions and offers broad functional group tolerance. In-depth mechanistic investigation supports the involvement of radical pathways. Furthermore, the synthetic utility of this methodology is portrayed through gram-scale synthesis | ||
| 650 | 4 | |a Journal Article | |
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| 700 | 1 | |a Mandal, Anirban |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Yu |e verfasserin |4 aut | |
| 700 | 1 | |a Hersh, William H |e verfasserin |4 aut | |
| 700 | 1 | |a Das, Sajal |e verfasserin |4 aut | |
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