An All-Climate Nonaqueous Hydrogen Gas-Proton Battery
Rechargeable hydrogen gas batteries, driven by hydrogen evolution and oxidation reactions (HER/HOR), are emerging grid-scale energy storage technologies owing to their low cost and superb cycle life. However, compared with aqueous electrolytes, the HER/HOR activities in nonaqueous electrolytes have rarely been studied. Here, for the first time, we develop a nonaqueous proton electrolyte (NAPE) for a high-performance hydrogen gas-proton battery for all-climate energy storage applications. The advanced nonaqueous hydrogen gas-proton battery (NAHPB) assembled with a representative V2(PO4)3 cathode and H2 anode in a NAPE exhibits a high discharge capacity of 165 mAh g-1 at 1 C at room temperature. It also efficiently operates under all-climate conditions (from -30 to +70 °C) with an excellent electrochemical performance. Our findings offer a new direction for designing nonaqueous proton batteries in a wide temperature range.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:24 |
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| Enthalten in: |
Nano letters - 24(2024), 5 vom: 07. Feb., Seite 1729-1737 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Zhang, Kai [VerfasserIn] |
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| Links: |
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| Themen: |
Hydrogen gas batteries |
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| Anmerkungen: |
Date Revised 07.02.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.nanolett.3c04566 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM367796201 |
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| 520 | |a Rechargeable hydrogen gas batteries, driven by hydrogen evolution and oxidation reactions (HER/HOR), are emerging grid-scale energy storage technologies owing to their low cost and superb cycle life. However, compared with aqueous electrolytes, the HER/HOR activities in nonaqueous electrolytes have rarely been studied. Here, for the first time, we develop a nonaqueous proton electrolyte (NAPE) for a high-performance hydrogen gas-proton battery for all-climate energy storage applications. The advanced nonaqueous hydrogen gas-proton battery (NAHPB) assembled with a representative V2(PO4)3 cathode and H2 anode in a NAPE exhibits a high discharge capacity of 165 mAh g-1 at 1 C at room temperature. It also efficiently operates under all-climate conditions (from -30 to +70 °C) with an excellent electrochemical performance. Our findings offer a new direction for designing nonaqueous proton batteries in a wide temperature range | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a hydrogen gas batteries | |
| 650 | 4 | |a large-scale energy storage | |
| 650 | 4 | |a nonaqueous proton electrolyte | |
| 650 | 4 | |a solvation structure | |
| 650 | 4 | |a wide temperature range | |
| 700 | 1 | |a Liu, Zaichun |e verfasserin |4 aut | |
| 700 | 1 | |a Khan, Nawab Ali |e verfasserin |4 aut | |
| 700 | 1 | |a Ma, Yirui |e verfasserin |4 aut | |
| 700 | 1 | |a Xie, Zehui |e verfasserin |4 aut | |
| 700 | 1 | |a Xu, Jingwen |e verfasserin |4 aut | |
| 700 | 1 | |a Jiang, Taoli |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Hongxu |e verfasserin |4 aut | |
| 700 | 1 | |a Zhu, Zhengxin |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Shuang |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Weiping |e verfasserin |4 aut | |
| 700 | 1 | |a Meng, Yahan |e verfasserin |4 aut | |
| 700 | 1 | |a Peng, Qia |e verfasserin |4 aut | |
| 700 | 1 | |a Zheng, Xinhua |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Mingming |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Wei |e verfasserin |4 aut | |
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