Visible-Light-Induced Decarboxylative Aminosulfonylation of (Hetero)aryl Carboxylic Oxime Esters
Sulfonamides are important structures in pharmaceuticals, agrochemicals, and organocatalysts, yet the rapid and benign synthesis of these compounds is still a great challenge. Herein we report a photoinduced method for synthesizing sulfonamides from (hetero)aryl carboxylic acid oxime esters. This reaction proceeds via one-pot cascade radical-radical cross-coupling by energy-transfer-mediated photocatalysis. A wide substrate scope including (hetero)aryl substrates and late-stage modification of pharmaceutical molecular entities reveal its generality.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2024 |
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Erschienen: |
2024 |
Enthalten in: |
Zur Gesamtaufnahme - volume:26 |
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Enthalten in: |
Organic letters - 26(2024), 3 vom: 26. Jan., Seite 713-718 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Zhuang, Zhen [VerfasserIn] |
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Anmerkungen: |
Date Revised 26.01.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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doi: |
10.1021/acs.orglett.3c04142 |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM367050439 |
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700 | 1 | |a Zhong, Yuanchen |e verfasserin |4 aut | |
700 | 1 | |a He, Qian |e verfasserin |4 aut | |
700 | 1 | |a Zhang, Xiaofei |e verfasserin |4 aut | |
700 | 1 | |a Yang, Chunhao |e verfasserin |4 aut | |
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