A protocol for the stereoselective synthesis of a Star of David [2]catenane
Copyright © 2023 The Author(s). Published by Elsevier Inc. All rights reserved..
Most complex prime links exhibit inherent topological chirality, yet their high stereoinduction remains a rare occurrence. Here, we present a protocol for the stereoselective synthesis of a molecular link comprising two triple entwined rings. We describe steps for constructing the precursor circular helicate, performing ring closure metathesis, and demetallation. We also outline procedures for bio-beads separation and data analysis. This protocol holds promise for applications in molecular nanotopology. For complete details on the use and execution of this protocol, please refer to Zhang et al. (2022).1.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2024 |
|---|---|
| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:5 |
|---|---|
| Enthalten in: |
STAR protocols - 5(2024), 1 vom: 15. März, Seite 102821 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Ye, Weitao [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
Anthracenes |
|---|
| Anmerkungen: |
Date Completed 20.03.2024 Date Revised 20.03.2024 published: Print-Electronic Citation Status MEDLINE |
|---|
| doi: |
10.1016/j.xpro.2023.102821 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM366754653 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM366754653 | ||
| 003 | DE-627 | ||
| 005 | 20240320233914.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 240114s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.xpro.2023.102821 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1337.xml |
| 035 | |a (DE-627)NLM366754653 | ||
| 035 | |a (NLM)38184851 | ||
| 035 | |a (PII)S2666-1667(23)00788-8 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Ye, Weitao |e verfasserin |4 aut | |
| 245 | 1 | 2 | |a A protocol for the stereoselective synthesis of a Star of David [2]catenane |
| 264 | 1 | |c 2024 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 20.03.2024 | ||
| 500 | |a Date Revised 20.03.2024 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a Copyright © 2023 The Author(s). Published by Elsevier Inc. All rights reserved. | ||
| 520 | |a Most complex prime links exhibit inherent topological chirality, yet their high stereoinduction remains a rare occurrence. Here, we present a protocol for the stereoselective synthesis of a molecular link comprising two triple entwined rings. We describe steps for constructing the precursor circular helicate, performing ring closure metathesis, and demetallation. We also outline procedures for bio-beads separation and data analysis. This protocol holds promise for applications in molecular nanotopology. For complete details on the use and execution of this protocol, please refer to Zhang et al. (2022).1 | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Chemistry | |
| 650 | 4 | |a Material sciences | |
| 650 | 7 | |a catenane |2 NLM | |
| 650 | 7 | |a Anthracenes |2 NLM | |
| 650 | 7 | |a Catenanes |2 NLM | |
| 700 | 1 | |a Feng, Hai-Na |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Zhi-Hui |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Liang |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t STAR protocols |d 2020 |g 5(2024), 1 vom: 15. März, Seite 102821 |w (DE-627)NLM31262266X |x 2666-1667 |7 nnns |
| 773 | 1 | 8 | |g volume:5 |g year:2024 |g number:1 |g day:15 |g month:03 |g pages:102821 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1016/j.xpro.2023.102821 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 5 |j 2024 |e 1 |b 15 |c 03 |h 102821 | ||