Ultrathin Two-dimensional Layered Composite Carbosilicates from in situ Unzipped Carbon Nanotubes and Exfoliated Bulk Silica
© 2023 Wiley-VCH GmbH..
A key task in today's inorganic synthetic chemistry is to develop effective reactions, routes, and associated techniques aiming to create new functional materials with specifically desired multilevel structures and properties. Herein, we report an ultrathin two-dimensional layered composite of graphene ribbon and silicate via a simple and scalable one-pot reaction, which leads to the creation of a novel carbon-metal-silicate hybrid family: carbosilicate. The graphene ribbon is in situ formed by unzipping carbon nanotubes, while the ultrathin silicate is in situ obtained from bulk silica or commercial glass; transition metals (Fe or Ni) oxidized by water act as bridging agent, covalently bonding the two structures. The unprecedented structure combines the superior properties of the silicate and the nanocarbon, which triggers some specific novel properties. All processes during synthesis are complementary to each other. The associated synergistic chemistry could stimulate the discovery of a large class of more interesting, functionalized structures and materials.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:63 |
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| Enthalten in: |
Angewandte Chemie (International ed. in English) - 63(2024), 7 vom: 12. Feb., Seite e202318043 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ding, Yuxiao [VerfasserIn] |
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| Links: |
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| Themen: |
Carbosilicate |
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| Anmerkungen: |
Date Revised 06.02.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1002/anie.202318043 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM366263331 |
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| 520 | |a A key task in today's inorganic synthetic chemistry is to develop effective reactions, routes, and associated techniques aiming to create new functional materials with specifically desired multilevel structures and properties. Herein, we report an ultrathin two-dimensional layered composite of graphene ribbon and silicate via a simple and scalable one-pot reaction, which leads to the creation of a novel carbon-metal-silicate hybrid family: carbosilicate. The graphene ribbon is in situ formed by unzipping carbon nanotubes, while the ultrathin silicate is in situ obtained from bulk silica or commercial glass; transition metals (Fe or Ni) oxidized by water act as bridging agent, covalently bonding the two structures. The unprecedented structure combines the superior properties of the silicate and the nanocarbon, which triggers some specific novel properties. All processes during synthesis are complementary to each other. The associated synergistic chemistry could stimulate the discovery of a large class of more interesting, functionalized structures and materials | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Carbosilicate | |
| 650 | 4 | |a Graphene Nanoribbon | |
| 650 | 4 | |a Nanocarbon | |
| 650 | 4 | |a Silicate | |
| 650 | 4 | |a Ultrathin 2D Material | |
| 700 | 1 | |a Liu, Yumeng |e verfasserin |4 aut | |
| 700 | 1 | |a Klyushin, Alexander Y |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Liyun |e verfasserin |4 aut | |
| 700 | 1 | |a Han, Gengxu |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Zigeng |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Jianying |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Bingsen |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Kang |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Wei |e verfasserin |4 aut | |
| 700 | 1 | |a Eichel, Rüdiger-A |e verfasserin |4 aut | |
| 700 | 1 | |a Sun, Xiaoyan |e verfasserin |4 aut | |
| 700 | 1 | |a Qiao, Zhen-An |e verfasserin |4 aut | |
| 700 | 1 | |a Heumann, Saskia |e verfasserin |4 aut | |
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