The Lewis superacidic aluminium cation : [(NHC)Al(C6F5)2
The aluminium salt [(NHC)Al(tol)(C6F5)2][B(C6F5)4], (NHC = C3H2(N(iPr2C6H3))2) is shown to behave as a Lewis superacid as it abstracts fluoride from [SbF6]-. It also acts as a Lewis acid catalyst for hydrosilyation, hydrodefluorination and Friedel-Crafts reactions.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2024 |
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| Erschienen: |
2024 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:60 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 60(2024), 6 vom: 16. Jan., Seite 698-701 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ju, Shaoying [VerfasserIn] |
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| Anmerkungen: |
Date Revised 16.01.2024 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d3cc05440c |
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NLM366019996 |
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| 520 | |a The aluminium salt [(NHC)Al(tol)(C6F5)2][B(C6F5)4], (NHC = C3H2(N(iPr2C6H3))2) is shown to behave as a Lewis superacid as it abstracts fluoride from [SbF6]-. It also acts as a Lewis acid catalyst for hydrosilyation, hydrodefluorination and Friedel-Crafts reactions | ||
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| 700 | 1 | |a Tang, Beili |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Liu Leo |e verfasserin |4 aut | |
| 700 | 1 | |a Stephan, Douglas W |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Yile |e verfasserin |4 aut | |
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