Hierarchical Porous Activated Carbon from Wheat Bran Agro-Waste : Applications in Carbon Dioxide Capture, Dye Removal, Oxygen and Hydrogen Evolution Reactions
© 2023 Wiley-VCH GmbH..
This work reports an efficient method for facile synthesis of hierarchically porous carbon (WB-AC) utilizing wheat bran waste. Obtained carbon showed 2.47 mmol g-1 CO2 capture capacity with good CO2 /N2 selectivity and 27.35 to 29.90 kJ mol-1 isosteric heat of adsorption. Rapid removal of MO dye was observed with a capacity of ~555 mg g-1 . Moreover, WB-AC demonstrated a good OER activity with 0.35 V low overpotential at 5 mA cm-2 and a Tafel slope of 115 mV dec-1 . It also exhibited high electrocatalytic HER activity with 57 mV overpotential at 10 mA cm-2 and a Tafel slope of 82.6 mV dec-1 . The large SSA (757 m2 g-1 ) and total pore volume (0.3696 cm3 g-1 ) result from N2 activation contributing to selective CO2 uptake, high and rapid dye removal capacity and superior electrochemical activity (OER/HER), suggesting the use of WB-AC as cost effective adsorbent and metal free electrocatalyst.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2024 |
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Erschienen: |
2024 |
Enthalten in: |
Zur Gesamtaufnahme - volume:89 |
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Enthalten in: |
ChemPlusChem - 89(2024), 3 vom: 01. März, Seite e202300373 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Koli, Amruta [VerfasserIn] |
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Links: |
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Themen: |
Carbon dioxide capture |
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Anmerkungen: |
Date Revised 18.03.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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doi: |
10.1002/cplu.202300373 |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM364016981 |
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520 | |a © 2023 Wiley-VCH GmbH. | ||
520 | |a This work reports an efficient method for facile synthesis of hierarchically porous carbon (WB-AC) utilizing wheat bran waste. Obtained carbon showed 2.47 mmol g-1 CO2 capture capacity with good CO2 /N2 selectivity and 27.35 to 29.90 kJ mol-1 isosteric heat of adsorption. Rapid removal of MO dye was observed with a capacity of ~555 mg g-1 . Moreover, WB-AC demonstrated a good OER activity with 0.35 V low overpotential at 5 mA cm-2 and a Tafel slope of 115 mV dec-1 . It also exhibited high electrocatalytic HER activity with 57 mV overpotential at 10 mA cm-2 and a Tafel slope of 82.6 mV dec-1 . The large SSA (757 m2 g-1 ) and total pore volume (0.3696 cm3 g-1 ) result from N2 activation contributing to selective CO2 uptake, high and rapid dye removal capacity and superior electrochemical activity (OER/HER), suggesting the use of WB-AC as cost effective adsorbent and metal free electrocatalyst | ||
650 | 4 | |a Journal Article | |
650 | 4 | |a carbon dioxide capture | |
650 | 4 | |a dye removal | |
650 | 4 | |a electrocatalysis | |
650 | 4 | |a hierarchical porous carbon | |
650 | 4 | |a waste valorization | |
700 | 1 | |a Kumar, Abhishek |e verfasserin |4 aut | |
700 | 1 | |a Pattanshetti, Akshata |e verfasserin |4 aut | |
700 | 1 | |a Supale, Amit |e verfasserin |4 aut | |
700 | 1 | |a Garadkar, Kalyanrao |e verfasserin |4 aut | |
700 | 1 | |a Shen, Jian |e verfasserin |4 aut | |
700 | 1 | |a Shaikh, Jasmin |e verfasserin |4 aut | |
700 | 1 | |a Praserthdam, Supareak |e verfasserin |4 aut | |
700 | 1 | |a Motkuri, Radha Kishan |e verfasserin |4 aut | |
700 | 1 | |a Sabale, Sandip |e verfasserin |4 aut | |
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