Nano-silica from white silica sand functionalized with PANI-SDS (SiO2/PANI-SDS) as an adsorbent for the elimination of methylene blue from aqueous media
© 2023. The Author(s)..
Natural resources including sand are one of the best approaches for treating dye-polluted wastewater. The SiO2/PANI-SDS nanocomposite was synthesized by self-assembly and intermolecular interaction. The physicochemical features of the SiO2/PANI-SDS nanocomposite were explored by FT-IR, XRD, SEM, TEM, EDX, and N2 adsorption-desorption techniques to be evaluated as an adsorbent for the MB. The surface area of the SiO2/PANI-SDS is 23.317 m2/g, the pore size is 0.036 cm3/g, and the pore radius is 1.91 nm. Batch kinetic studies at different initial adsorbate, adsorbent and NaCl concentrations, and temperatures showed excellent pseudo-second-order. Several isotherm models were applied to evaluate the MB adsorption on the SiO2/PANI-SDS nanocomposite. According to R2 values the isotherm models were fitted in the following order: Langmuir > Dubinin-Radushkevich (D-R) > Freundlich. The adsorption/desorption process showed good reusability of the SiO2/PANI-SDS nanocomposite.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2023 |
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Erschienen: |
2023 |
Enthalten in: |
Zur Gesamtaufnahme - volume:13 |
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Enthalten in: |
Scientific reports - 13(2023), 1 vom: 31. Okt., Seite 18684 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Salem, Mohamed A [VerfasserIn] |
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Anmerkungen: |
Date Revised 03.11.2023 published: Electronic Citation Status PubMed-not-MEDLINE |
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doi: |
10.1038/s41598-023-45873-y |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM363995714 |
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520 | |a Natural resources including sand are one of the best approaches for treating dye-polluted wastewater. The SiO2/PANI-SDS nanocomposite was synthesized by self-assembly and intermolecular interaction. The physicochemical features of the SiO2/PANI-SDS nanocomposite were explored by FT-IR, XRD, SEM, TEM, EDX, and N2 adsorption-desorption techniques to be evaluated as an adsorbent for the MB. The surface area of the SiO2/PANI-SDS is 23.317 m2/g, the pore size is 0.036 cm3/g, and the pore radius is 1.91 nm. Batch kinetic studies at different initial adsorbate, adsorbent and NaCl concentrations, and temperatures showed excellent pseudo-second-order. Several isotherm models were applied to evaluate the MB adsorption on the SiO2/PANI-SDS nanocomposite. According to R2 values the isotherm models were fitted in the following order: Langmuir > Dubinin-Radushkevich (D-R) > Freundlich. The adsorption/desorption process showed good reusability of the SiO2/PANI-SDS nanocomposite | ||
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