Synthesis of lignin nanoparticle‑manganese dioxide complex and its adsorption of methyl orange
Copyright © 2023 Elsevier B.V. All rights reserved..
Lignin nanoparticles (LNPs) were synthesized using an anti-solvent method and subsequently loaded with manganese dioxide (MnO2) via potassium permanganate treatment, resulting in the formation of MnO2LNPs. An extensive investigation was conducted to elucidate the influence of MnO2@LNPs on the decolorization of methyl orange solution. The LNPs were successfully obtained by adjusting the preparation parameters, yielding particles exhibited average sizes ranging from 300 to 600 nm, and the synthesis process exhibited a high yield of up to 87.3% and excellent dispersion characteristics. Notably, LNPs size was reduced by decreasing initial concentration, increasing stirring rate, and adding water. In the acetone-water two-phase system, LNPs self-assembled into spherical particles driven by π-π interactions and hydrogen bond forces. Oxidation modification using potassium permanganate led to the formation of nanoscale MnO2, which effectively combined with LNPs. Remarkably, the resulting MnO2@LNPs demonstrated a two-fold increase in methyl orange adsorption capacity (227 mg/g) compared to unmodified LNPs. The process followed the Langmuir isotherm model and was exothermic.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2023 |
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Erschienen: |
2023 |
Enthalten in: |
Zur Gesamtaufnahme - volume:253 |
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Enthalten in: |
International journal of biological macromolecules - 253(2023), Pt 4 vom: 31. Dez., Seite 127012 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Guo, Tian-Shui [VerfasserIn] |
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Links: |
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Anmerkungen: |
Date Completed 29.11.2023 Date Revised 29.11.2023 published: Print-Electronic Citation Status MEDLINE |
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doi: |
10.1016/j.ijbiomac.2023.127012 |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM362311323 |
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520 | |a Copyright © 2023 Elsevier B.V. All rights reserved. | ||
520 | |a Lignin nanoparticles (LNPs) were synthesized using an anti-solvent method and subsequently loaded with manganese dioxide (MnO2) via potassium permanganate treatment, resulting in the formation of MnO2LNPs. An extensive investigation was conducted to elucidate the influence of MnO2@LNPs on the decolorization of methyl orange solution. The LNPs were successfully obtained by adjusting the preparation parameters, yielding particles exhibited average sizes ranging from 300 to 600 nm, and the synthesis process exhibited a high yield of up to 87.3% and excellent dispersion characteristics. Notably, LNPs size was reduced by decreasing initial concentration, increasing stirring rate, and adding water. In the acetone-water two-phase system, LNPs self-assembled into spherical particles driven by π-π interactions and hydrogen bond forces. Oxidation modification using potassium permanganate led to the formation of nanoscale MnO2, which effectively combined with LNPs. Remarkably, the resulting MnO2@LNPs demonstrated a two-fold increase in methyl orange adsorption capacity (227 mg/g) compared to unmodified LNPs. The process followed the Langmuir isotherm model and was exothermic | ||
650 | 4 | |a Journal Article | |
650 | 4 | |a Formic acid lignin | |
650 | 4 | |a Methyl orange adsorption | |
650 | 4 | |a Nanoparticles | |
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700 | 1 | |a Cui, Hua-Min |e verfasserin |4 aut | |
700 | 1 | |a Yu, Qiong-Fen |e verfasserin |4 aut | |
700 | 1 | |a Li, Ming-Fei |e verfasserin |4 aut | |
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