Oxidative Cleavage and Fluoromethylthiolation of C═C Bonds : A General Route toward Mono-, Di-, and Trifluoromethylthioesters from Alkenes
A novel oxidative cleavage and fluoromethylthiolation reaction of C═C bonds has been developed that represents the first and general method for the preparation of mono-, di-, and trifluoromethylthioesters from alkenes. The protocol features excellent product selectivity and substrate suitability. Various observations suggested that the protocol proceeded via a two-step radical process and that aldehyde was the key intermediate. What's more meaningful is that this route provides a new direction for converting alkenes into higher-value-added carbonyl-containing chemicals.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:25 |
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| Enthalten in: |
Organic letters - 25(2023), 32 vom: 18. Aug., Seite 5984-5988 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Kou, Li-Gang [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Revised 18.08.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.orglett.3c02101 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM360483097 |
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| 245 | 1 | 0 | |a Oxidative Cleavage and Fluoromethylthiolation of C═C Bonds |b A General Route toward Mono-, Di-, and Trifluoromethylthioesters from Alkenes |
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| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a A novel oxidative cleavage and fluoromethylthiolation reaction of C═C bonds has been developed that represents the first and general method for the preparation of mono-, di-, and trifluoromethylthioesters from alkenes. The protocol features excellent product selectivity and substrate suitability. Various observations suggested that the protocol proceeded via a two-step radical process and that aldehyde was the key intermediate. What's more meaningful is that this route provides a new direction for converting alkenes into higher-value-added carbonyl-containing chemicals | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Guo, Shi-Huan |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Ya-Ru |e verfasserin |4 aut | |
| 700 | 1 | |a Yue, Tianli |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Yong-Qiang |e verfasserin |4 aut | |
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