Structural Change and Radical Generation of a Cadmium-Based Metal-Organic Framework Induced by an Electric Field
Herein we report the structural change and radical generation of a cadmium-based metal-organic framework (Cd-MOF) induced by external electric fields. Under a weaker single electric field, different coordination modes of Cd-L lead to 3D → 2D structural change. Under stronger superposed electric fields, Cd-MOF was excited to produce a stable free radical. This study will provide a new avenue for the controlled assembly of MOFs.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:62 |
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| Enthalten in: |
Inorganic chemistry - 62(2023), 23 vom: 12. Juni, Seite 8784-8788 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Jin, Guo-Xia [VerfasserIn] |
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| Anmerkungen: |
Date Completed 12.06.2023 Date Revised 12.06.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.inorgchem.3c01256 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM357554191 |
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| 520 | |a Herein we report the structural change and radical generation of a cadmium-based metal-organic framework (Cd-MOF) induced by external electric fields. Under a weaker single electric field, different coordination modes of Cd-L lead to 3D → 2D structural change. Under stronger superposed electric fields, Cd-MOF was excited to produce a stable free radical. This study will provide a new avenue for the controlled assembly of MOFs | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Su, Zi-Lin |e verfasserin |4 aut | |
| 700 | 1 | |a Han, Cong-Cong |e verfasserin |4 aut | |
| 700 | 1 | |a Han, Li-Cong |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Fu-Bo |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Xiangwen |e verfasserin |4 aut | |
| 700 | 1 | |a Zhao, Xianliang |e verfasserin |4 aut | |
| 700 | 1 | |a Cai, Meichao |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Haiying |e verfasserin |4 aut | |
| 700 | 1 | |a Ma, Jian-Ping |e verfasserin |4 aut | |
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