CAl11- : a molecular rotor with a quasi-planar tetracoordinate carbon
In this work, we analyzed the bonding and fluxional character of the global minimum of CAl11-. Its structure is formed by two stacked layers, one of them resembles the well-known planar tetracoordinate carbon CAl4 on top of a hexagonal AlAl6 wheel. Our results show that the CAl4 fragment rotates freely around the central axis. The exceptional stability and fluxionality of CAl11- derive from its particular electron distribution.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:59 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 59(2023), 33 vom: 20. Apr., Seite 4966-4969 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Bai, Li-Xia [VerfasserIn] |
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| Anmerkungen: |
Date Completed 20.04.2023 Date Revised 20.04.2023 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d3cc00855j |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM355194635 |
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| 245 | 1 | 0 | |a CAl11- |b a molecular rotor with a quasi-planar tetracoordinate carbon |
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| 500 | |a Date Revised 20.04.2023 | ||
| 500 | |a published: Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a In this work, we analyzed the bonding and fluxional character of the global minimum of CAl11-. Its structure is formed by two stacked layers, one of them resembles the well-known planar tetracoordinate carbon CAl4 on top of a hexagonal AlAl6 wheel. Our results show that the CAl4 fragment rotates freely around the central axis. The exceptional stability and fluxionality of CAl11- derive from its particular electron distribution | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Barroso, Jorge |e verfasserin |4 aut | |
| 700 | 1 | |a Orozco-Ic, Mesías |e verfasserin |4 aut | |
| 700 | 1 | |a Ortiz-Chi, Filiberto |e verfasserin |4 aut | |
| 700 | 1 | |a Guo, Jin-Chang |e verfasserin |4 aut | |
| 700 | 1 | |a Merino, Gabriel |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemical communications (Cambridge, England) |d 1998 |g 59(2023), 33 vom: 20. Apr., Seite 4966-4969 |w (DE-627)NLM095512322 |x 1364-548X |7 nnns |
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