A Bipyridine-Promoted Csp3 -Csp3 Coupling of beta-Chlorophenones
© 2023 Wiley-VCH GmbH..
A novel, direct Csp3 -Csp3 coupling reaction of β-chlorophenone with alkanes using 2-(tert-butylperoxy)-2-methylpropane (DTBP) as the oxidant and 2,2'-bipyridine (bpy) as the effective additive was developed. A variety of β-chloropropiophenones were well tolerated, and afforded alkylated products in moderate to good yields. A mechanistic study indicated a free radical pathway was involved in this alkyl-alkyl cross-coupling reaction.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:18 |
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| Enthalten in: |
Chemistry, an Asian journal - 18(2023), 8 vom: 17. Apr., Seite e202300030 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Li, Bao [VerfasserIn] |
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| Links: |
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| Themen: |
1,4-dioxane |
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| Anmerkungen: |
Date Completed 17.04.2023 Date Revised 17.04.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1002/asia.202300030 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM353756636 |
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| 245 | 1 | 2 | |a A Bipyridine-Promoted Csp3 -Csp3 Coupling of beta-Chlorophenones |
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| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a © 2023 Wiley-VCH GmbH. | ||
| 520 | |a A novel, direct Csp3 -Csp3 coupling reaction of β-chlorophenone with alkanes using 2-(tert-butylperoxy)-2-methylpropane (DTBP) as the oxidant and 2,2'-bipyridine (bpy) as the effective additive was developed. A variety of β-chloropropiophenones were well tolerated, and afforded alkylated products in moderate to good yields. A mechanistic study indicated a free radical pathway was involved in this alkyl-alkyl cross-coupling reaction | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a 1,4-dioxane | |
| 650 | 4 | |a 2,2′-bipyridine | |
| 650 | 4 | |a 2-(tert-butylperoxy)-2-methylpropane | |
| 650 | 4 | |a alkyl-alkyl cross-coupling | |
| 650 | 4 | |a radical | |
| 700 | 1 | |a Wang, Junrui |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Jie |e verfasserin |4 aut | |
| 700 | 1 | |a Zhao, Yingsheng |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemistry, an Asian journal |d 2006 |g 18(2023), 8 vom: 17. Apr., Seite e202300030 |w (DE-627)NLM169728706 |x 1861-471X |7 nnns |
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