Microencapsulation of n-tetradecane with poly (methyl methacrylate-co-methacrylic acid) shell by seeded emulsion polymerisation and its thermal energy storage characteristics
This study aims to enhance the latent heat storage properties of the microcapsules by altering the amount of crosslinking agent from 3 to 20%w/w, the core-to-shell ratio from 1:1 to 2:1, and the amount of initiator from 1 to 3%. The phase change material n-tetradecane (C-14) was microencapsulated by using poly (methyl methacrylate -co- methacrylic acid) as a shell material through an oil by water-seeded emulsion polymerisation technique. The structural, morphological, and thermal properties of microcapsules were evaluated by using Fourier transform infrared spectroscopy, optical microscopy, scanning electron microscopy, differential scanning calorimetry analysis, and thermogravimetric analysis. The average particle size of the microcapsules ranges from 01 to 15 µm. The results showed that the microcapsules have a higher melting enthalpy value of 127.3 ± 0.06 J/g with a microencapsulation efficiency of 66.72% when a 20% w/w crosslinker was used. The thermal stability of the phase change material (PCM) was increased by ∼30 ± 2 °C by encapsulation.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2023 |
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| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:40 |
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| Enthalten in: |
Journal of microencapsulation - 40(2023), 2 vom: 16. März, Seite 98-105 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Mahajan, U R [VerfasserIn] |
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| Links: |
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| Anmerkungen: |
Date Completed 27.03.2023 Date Revised 27.03.2023 published: Print-Electronic Citation Status MEDLINE |
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| doi: |
10.1080/02652048.2023.2175923 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM352448342 |
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| 100 | 1 | |a Mahajan, U R |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Microencapsulation of n-tetradecane with poly (methyl methacrylate-co-methacrylic acid) shell by seeded emulsion polymerisation and its thermal energy storage characteristics |
| 264 | 1 | |c 2023 | |
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| 500 | |a Date Completed 27.03.2023 | ||
| 500 | |a Date Revised 27.03.2023 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a This study aims to enhance the latent heat storage properties of the microcapsules by altering the amount of crosslinking agent from 3 to 20%w/w, the core-to-shell ratio from 1:1 to 2:1, and the amount of initiator from 1 to 3%. The phase change material n-tetradecane (C-14) was microencapsulated by using poly (methyl methacrylate -co- methacrylic acid) as a shell material through an oil by water-seeded emulsion polymerisation technique. The structural, morphological, and thermal properties of microcapsules were evaluated by using Fourier transform infrared spectroscopy, optical microscopy, scanning electron microscopy, differential scanning calorimetry analysis, and thermogravimetric analysis. The average particle size of the microcapsules ranges from 01 to 15 µm. The results showed that the microcapsules have a higher melting enthalpy value of 127.3 ± 0.06 J/g with a microencapsulation efficiency of 66.72% when a 20% w/w crosslinker was used. The thermal stability of the phase change material (PCM) was increased by ∼30 ± 2 °C by encapsulation | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a acrylic copolymer | |
| 650 | 4 | |a cold storage application | |
| 650 | 4 | |a enthalpy optimisation | |
| 650 | 4 | |a microencapsulation | |
| 650 | 4 | |a n-Tetradecane | |
| 650 | 7 | |a Polymethyl Methacrylate |2 NLM | |
| 650 | 7 | |a 9011-14-7 |2 NLM | |
| 650 | 7 | |a n-tetradecane |2 NLM | |
| 650 | 7 | |a 03LY784Y58 |2 NLM | |
| 650 | 7 | |a methacrylic acid |2 NLM | |
| 650 | 7 | |a 1CS02G8656 |2 NLM | |
| 650 | 7 | |a Emulsions |2 NLM | |
| 650 | 7 | |a Capsules |2 NLM | |
| 650 | 7 | |a Methacrylates |2 NLM | |
| 700 | 1 | |a Emmanuel, I |e verfasserin |4 aut | |
| 700 | 1 | |a Shrinivasa Rao, A |e verfasserin |4 aut | |
| 700 | 1 | |a Mhaske, S T |e verfasserin |4 aut | |
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